Isotermal Adsorpsi Ion Tembaga (II) Menggunakan Arang Tongkol Jagung (Zea mays L.) Teraktivasi Kalium Permanganat

Lisma Habiba, Nov Irmawati Inda, Prismawiryanti, Husain Sosidi, N. Sumarni, D. Puspitasari, Moh. Mirzan, Jusman
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Abstract

Corn cobs which generally only become waste can be processed into activated carbon and used for the absorption of heavy metals, such as copper(II) ions. This study aims to determine the morphology of corn cobs charcoal after activation, determine the isothermal adsorption model of copper (II) metal ions on corncob-activated carbon, and then determine the adsorption capacity of copper (II) metal ions on corncob-activated carbon. The morphology of the corncob-activated charcoal obtained was analyzed using Scanning Electron Microscopy (SEM). Isothermal adsorption of copper (II) ions was carried out with various concentrations of copper (II) ions of 5, 10, 20, 50, and 100 ppm. The results of the analysis using SEM showed that the surface shape of the corncob-activated charcoal is regular and has pores with a pore diameter obtained in the range between 1.08-1.26 m and 1.38-1.59 m. The mechanism of adsorption of copper (II) ions by corncob-activated charcoal using KMnO4, following the Freundlich isothermal model with a value of R2 0.9993 with an adsorption capacity of 51 x 10-4 mmol/L. The utilization of activated carbon from corn cobs that are activated by potassium permanganate is very effective for adsorbing copper metal ion pollutants through an adsorption mechanism on the surface of activated carbon.
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铜离子异热导体(II)使用玉米棒子木炭(Zea mays L)。激活高锰酸钾
通常只成为废物的玉米芯可以加工成活性炭,用于吸收重金属,如铜(II)离子。本研究旨在测定活化后玉米芯炭的形貌,确定铜(II)金属离子在玉米芯活性炭上的等温吸附模型,进而确定铜(II)金属离子在玉米芯活性炭上的吸附能力。用扫描电镜对制备的玉米芯活性炭的形貌进行了分析。铜(II)离子的等温吸附分别为5、10、20、50和100ppm。SEM分析结果表明,玉米芯活性炭表面形状规则,具有孔径在1.08 ~ 1.26 m和1.38 ~ 1.59 m之间的孔隙。以KMnO4为原料的玉米芯活性炭吸附铜(II)离子的机理符合Freundlich等温模型,吸附量为51 × 10-4 mmol/L,吸附量R2为0.9993。利用经高锰酸钾活化的玉米芯活性炭,通过活性炭表面的吸附机制,对铜金属离子污染物进行了非常有效的吸附。
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