Hamid Irannezhad, J. Javanmardi, Ali Rasoolzadeh, K. Mehrabi, A. Mohammadi
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引用次数: 4
Abstract
One of the promising applications of clathrate/gas hydrates is the transport and storage of natural gas. Semi-clathrate hydrates have received more attention due to milder pressure/temperature stability conditions compared to ordinary clathrate hydrates. The most commonly reported semi-clathrate hydrates are formed from a combination of gas + water + quaternary ammonium salts. In this work, a total of 53 equilibrium data for semi-clathrate hydrates of methane + TetraButylAmmonium Bromide (TBAB)/TetraButylAmmonium Acetate (TBAA) aqueous solutions were experimentally measured. For TBAB, three concentrations including 0.0350, 0.0490, and 0.1500 mass fractions were used. For TBAA, a solution with a 0.0990 mass fraction was used. Additionally, the modified Chen–Guo model was applied to calculate the hydrate phase equilibrium conditions of methane + TBAB/TBAA aqueous solutions. The model can accurately calculate the aforementioned semi-clathrate hydrate phase equilibrium conditions with the Average Absolute Deviations ((AAD)T and (AAD)P) of 0.1 K and 0.08 MPa, respectively. The temperature increments for 0.0350, 0.0490, and 0.1500 mass fractions of TBAB are 7.7, 9.4, and 13.5 K, respectively. This value for 0.0990 mass fraction of TBAA is 6.2 K. Therefore, it is concluded that TBAB is a stronger hydrate promoter compared to TBAA.
期刊介绍：
OGST - Revue d''IFP Energies nouvelles is a journal concerning all disciplines and fields relevant to exploration, production, refining, petrochemicals, and the use and economics of petroleum, natural gas, and other sources of energy, in particular alternative energies with in view of the energy transition.
OGST - Revue d''IFP Energies nouvelles has an Editorial Committee made up of 15 leading European personalities from universities and from industry, and is indexed in the major international bibliographical databases.
The journal publishes review articles, in English or in French, and topical issues, giving an overview of the contributions of complementary disciplines in tackling contemporary problems. Each article includes a detailed abstract in English. However, a French translation of the summaries can be provided to readers on request. Summaries of all papers published in the revue from 1974 can be consulted on this site. Over 1 000 papers that have been published since 1997 are freely available in full text form (as pdf files). Currently, over 10 000 downloads are recorded per month.
Researchers in the above fields are invited to submit an article. Rigorous selection of the articles is ensured by a review process that involves IFPEN and external experts as well as the members of the editorial committee. It is preferable to submit the articles in English, either as independent papers or in association with one of the upcoming topical issues.
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