Kinetics and Isotherm Studies on Adsorption of Hexavalent Chromium Using Activated Carbon from Water Hyacinth

IF 1 Q4 CHEMISTRY, MULTIDISCIPLINARY Chemistry & Chemical Technology Pub Date : 2021-02-15 DOI:10.23939/CHCHT15.01.001
Angelica Angeles Macalalad, Quennie Rose Ebete, Dominic Gutierrez, Madelaine Ramos, B. J. A. Magoling
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引用次数: 2

Abstract

The present study is focused on the use of activated carbon derived from water hyacinth (WH-AC) as adsorbent for the removal of Cr(VI) from aqueous solution. The optimized WH-AC was found to be mesoporous and considered as granular. The surface area of 11.564 m2/g was found to have a good adsorption capacity. The adsorption data of the optimized WH-AC followed a pseudo-second order kinetics and the Freundlich isotherm model. Based on the correlation coefficient obtained from pseudo-second-order kinetic model, the R2 values were all above 0.99, which is closer to unity of one (1) indicating that it followed a chemisorption process. The adsorption capacity of WH-AC increased from 1.98 to 4.68 mg/g when adsorbate concentration increased from 20 to 50 mg/l. The overall study proved that the adsorption by activated carbon derived from water hyacinth can be an alternative and efficient technique in hexavalent chromium removal.
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水葫芦活性炭吸附六价铬的动力学及等温线研究
本文主要研究了水葫芦活性炭(WH-AC)作为吸附剂去除水溶液中的铬(VI)。优化后的WH-AC为介孔颗粒状。在11.564 m2/g的表面积上发现其具有良好的吸附能力。优化后的WH-AC吸附数据符合准二级动力学和Freundlich等温模型。根据拟二级动力学模型得到的相关系数,R2值均在0.99以上,更接近于1(1)的单位,说明其发生了化学吸附过程。当吸附浓度从20 mg/l增加到50 mg/l时,WH-AC的吸附量从1.98 mg/g增加到4.68 mg/g。研究结果表明,水葫芦活性炭对六价铬的吸附是一种有效的替代技术。
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来源期刊
Chemistry & Chemical Technology
Chemistry & Chemical Technology CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.70
自引率
44.40%
发文量
60
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