Study on the microstructure and corrosion behavior of Mg–(4 − x)Gd–xY–2Zn (x = 0, 2, 4 wt%) alloy

Yunhao Wang, Zili Liu, Xiqin Liu, Huanjian Xie, Yong Shi, Fang Liu, Jian Li
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引用次数: 1

Abstract

The relationship between the corrosion behavior of Mg–Gd–Y–Zn alloy and the content of rare earth elements was investigated. The results show that the Mg–4Gd–2Zn (VZ42) contains only α‐Mg matrix and W phase, while there are α‐Mg matrix, W phase and X phase in Mg–2Gd–2Y–2Zn (VWZ) and Mg–4Y–2Zn (WZ42). The corrosion rates measured by weight loss of VZ42, VWZ, and WZ42 are 8.17, 4.49, and 6.05 mm/year, respectively. Through the observation of microstructure, it is found that the corrosion first occurs around the W phase, which means that the micro galvanic effect caused by the W phase is more serious than that of the X phase. The more W phase, the greater the corrosion rate of the alloy. But continuously distributed layered X phase will form a barrier and protect α‐Mg from corrosion. It is found that different distribution of the second phase will also lead to different corrosion resistance.
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Mg -(4−x) Gd-xY-2Zn (x = 0,2,4 wt%)合金组织与腐蚀行为研究
研究了Mg-Gd-Y-Zn合金的腐蚀行为与稀土元素含量的关系。结果表明:Mg - 4gd - 2zn (VZ42)中只含有α‐Mg基体和W相,而Mg - 2gd - 2y - 2zn (VWZ)和Mg - 4y - 2zn (WZ42)中含有α‐Mg基体、W相和X相。VZ42、VWZ和WZ42的失重腐蚀速率分别为8.17、4.49和6.05 mm/年。通过显微组织观察发现,腐蚀首先发生在W相周围,这意味着W相引起的微电偶效应比X相引起的微电偶效应更严重。W相越多,合金的腐蚀速率越大。但连续分布的层状X相会形成屏障,保护α‐Mg不受腐蚀。研究发现,不同的第二相分布也会导致不同的耐蚀性。
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