One-Pot Synthesis of Metallopyrazinoporphyrazines Using 2,3-Diaminomaleonitrile and 1,2-Dicarbonyl Compounds Accelerated by Microwave Irradiation

A. Maleki, A. Rezayan
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引用次数: 5

Abstract

A one-pot microwave-assisted synthesis of metallopyrazinoporphyrazines as porphyrazine derivatives carrying six-membered pyrazine rings annulated at the periphery of the tetrapyrrolic macrocycle is described starting from 2,3-diaminomaleonitrile, 1,2-dicarbonyl compounds, metal salts, and urea.
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微波加速2,3-二氨基马来腈和1,2-二羰基化合物一锅法合成金属吡嗪卟啉类化合物
以2,3-二氨基马来腈、1,2-二羰基化合物、金属盐和尿素为起始原料,微波辅助一锅法合成金属吡嗪卟啉衍生物,该卟啉衍生物携带六元吡嗪环,环在四吡啶大环的外围。
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