On-Line Estimation of Conversion and the Molecular Weight Distribution in Batch Methyl Methacrylate Solution Polymerization

M. F. Ellis, T. W. Taylor, K. Jensen
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引用次数: 3

Abstract

An on-line measurement scheme for the estimation of monomer conversion, initiator conversion, temperature, and the entire molecular weight distribution (MWD) in batch methyl methacrylate solution polymerization has been developed. The measurement scheme is based on an extended Kalman filter, a detailed polymerization model, and uses measurements of monomer conversion from a densitometer, temperature measurements, and MWD measurements from an on-line gel permeation chromatograph (GPC). The use of the measuring devices and the computer interfacing requirements are discussed. Experimental results are presented which illustrate the measurement scheme's ability to estimate bimodal MWD's.
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间歇甲基丙烯酸甲酯溶液聚合过程中转化率和分子量分布的在线估计
提出了一种在线测量甲基丙烯酸甲酯溶液间歇聚合过程中单体转化率、引发剂转化率、温度和总分子量分布的方法。测量方案基于扩展的卡尔曼滤波,详细的聚合模型,并使用密度计测量单体转化,温度测量和在线凝胶渗透色谱仪(GPC)的随钻测井测量。讨论了测量装置的使用和计算机接口要求。实验结果表明,该测量方案具有估计双峰随钻测井曲线的能力。
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