TiO2 Doped with Metal Ions as the UV Photocatalyts for Ciba-Red Wastewater Treatment

C. Sun, Xianxiang Sun
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引用次数: 1

Abstract

Five kinds of TiO2 photo catalysts doped with Fe3+, Ag+, Eu3+, Ni2+, respectively, by Sol-Gel method from Ti(OC4H9)4, were prepared to investigate different UV photo catalytic activity in the Ciba-Red aqueous solution. The effects of pH and the size of titania particles on the photo catalytic degradation rate of Ciba-Red aqueous solution were studied. TiO2 doped with the bimetal ions, Fe3+ and Eu3+, showed best photo catalytic activity than other catalysts. The photocalytic degradation showed a quasi-first-order reaction kinetics. The mechanism of the photo catalytic degradation was also discussed.
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金属离子掺杂TiO2作为紫外光催化剂处理汽巴红废水
以Ti(OC4H9)4为原料,采用溶胶-凝胶法制备了5种分别掺杂Fe3+、Ag+、Eu3+、Ni2+的TiO2光催化剂,考察了其在Ciba-Red水溶液中的紫外光催化活性。研究了pH和二氧化钛颗粒大小对汽巴红水溶液光催化降解率的影响。掺杂Fe3+和Eu3+双金属离子的TiO2表现出最好的光催化活性。光催化降解表现为准一级反应动力学。讨论了光催化降解的机理。
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