Visible Light Photocatalytic Activity of CeO2-ZnO-TiO2 Composites for the Degradation of Rhodamine B

S. Prabhu, T. Viswanathan, K. Jothivenkatachalam, K. Jeganathan
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引用次数: 29

Abstract

TiO2 plays a significant role in many applications including solar cell. Consecutively to absorb the low-energy radiation, it is very much essential to tune the optical property of TiO2. We fabricated CeO2-ZnO-TiO2 semiconductor composites by sol-gel method and achieved the absorption of lower energy radiation. The prepared composites were characterized by TG-DTA, UV-DRS, XRD, AFM, TEM and FESEM techniques. The particle and crystalline size of the composites was calculated using FESEM and XRD techniques, respectively. The photocatalytic activity of the synthesized composite for the degradation of Rhodamine B (RhB) under visible light irradiation was investigated. The photocatalytic degradation of RhB under various experimental conditions such as amount of catalyst, initial dye concentration and H2O2 amount was also demonstrated and the rate constant was calculated using L-H model.
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CeO2-ZnO-TiO2复合材料降解罗丹明B的可见光催化活性研究
TiO2在包括太阳能电池在内的许多应用中发挥着重要作用。因此,对TiO2的光学性质进行调整是非常必要的。采用溶胶-凝胶法制备了CeO2-ZnO-TiO2半导体复合材料,实现了对低能辐射的吸收。采用TG-DTA、UV-DRS、XRD、AFM、TEM和FESEM等技术对复合材料进行了表征。利用FESEM和XRD技术分别计算了复合材料的颗粒尺寸和晶粒尺寸。研究了合成的复合材料在可见光下降解罗丹明B (Rhodamine B, RhB)的光催化活性。考察了催化剂用量、染料初始浓度、H2O2用量等不同实验条件下光催化降解RhB的效果,并利用L-H模型计算了反应速率常数。
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