FABRICATION OF SAND/ZINC OXIDE/TITANIUM DIOXIDE NANOCOMPOSITE AS PHOTOCATALYST

Nur Jannah Idris
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引用次数: 2

Abstract

 In this work, a nanocomposite photocatalyst was fabricated by growing zinc oxide (ZnO) and titanium dioxide (TiO2) on the sand as a substrate. The initial sand/ZnO was fabricated via sol-gel immersion method for 4 h at 95℃. Furthermore, the sand/ZnO/TiO2 was fabricatedusing hydrothermal method for 5 h at 150℃. Based on field emission scanning electron microscopy (FESEM) analysis, the fabricated sand/ZnO/TiO2 consists of random formation of hexagonal ZnO nanorods and two pyramidal spindle ends of TiO2 nanorods. The addition of TiO2 on top of ZnO nanorods increased the number of active sites which enables more contaminants to be absorbed thus enhanced the photocatalysis process. Moreover, based on the micro-Raman spectra, the synthesized TiO2 was in rutile phase and the ZnO peak was unobservable due to the overlapping with TiO2 peak. Based on its morphological and structural properties, the fabricated sand/ZnO/TiO2 nanocomposite was potential to be applied as photocatalyst.
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砂/氧化锌/二氧化钛纳米复合材料光催化剂的制备
在本研究中,通过在沙子上生长氧化锌(ZnO)和二氧化钛(TiO2)作为衬底,制备了纳米复合光催化剂。采用溶胶-凝胶浸泡法制备初始砂/ZnO,温度为95℃,时间为4 h。在此基础上,采用水热法在150℃下制备了5 h的ZnO/TiO2 /砂。基于场发射扫描电镜(FESEM)分析,制备的沙子/ZnO/TiO2由随机形成的六边形ZnO纳米棒和两个锥体形的TiO2纳米棒组成。在ZnO纳米棒上添加TiO2增加了活性位点的数量,从而使更多的污染物被吸收,从而增强了光催化过程。显微拉曼光谱分析表明,合成的TiO2为金红石相,由于ZnO峰与TiO2峰重叠,无法观察到ZnO峰。基于砂/ZnO/TiO2纳米复合材料的形态和结构特性,该复合材料具有作为光催化剂的应用潜力。
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审稿时长
12 weeks
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