Synthesis of Nano-Emulsion with Allyl-Type Sodium Succinate Diester Emulsifier

Yaohua Wei, Xiulan Xin, Yang Yu, Haibao Zhu
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Abstract

In this study 50-70nm Nano-emulsion was synthesized by semi-continuous seeding emulsion with the compound of the different long-chain of carbon of the Allyl-type sodium Succinate Diester Emulsifier and traditional emulsifier. The type and amount of emulsifier, initiator and monomer ratio on the amount and impact of acrylic emulsion were discussed. The results showed that the obtained acrylic emulsion with the presence of polymerizable emulsion has significant lower water absorption and greater stability than that with the presence of traditional emulsifier. Measuring the solid content , particle size, stability, morphology, glass transition temperature and water absorption of the emulsion with the three types of allyl-type polymerizable emulsifier(sodium octyl allyl succinate (DOAS), sodium dodecyl succinate (SDAS) , tetradecyl sodium allyl succinate (TSAS)), considering various factors, sodium dodecyl allyl succinate has better emulsification.
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烯丙基型琥珀酸二酯钠乳化剂合成纳米乳液
本研究以烯丙基型琥珀酸二酯钠乳化剂与传统乳化剂的不同长链碳的化合物为原料,采用半连续播种乳化法制备了50-70nm的纳米乳化剂。探讨了乳化剂的种类、用量、引发剂用量和单体配比对丙烯酸乳液的用量及影响。结果表明,与传统乳化剂相比,可聚合乳液存在时所制得的丙烯酸乳液吸水率明显降低,稳定性更高。用三种烯丙基型可聚合乳化剂(丁二辛基烯丙基钠(DOAS)、十二烷基丁二酸钠(SDAS)、十四烷基丁二烯丙基钠(TSAS))测定乳液的固含量、粒径、稳定性、形貌、玻璃化转变温度和吸水率,综合各种因素,丁二烯丙基钠具有较好的乳化效果。
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