{"title":"Reactivity of Cu(I) nacnac complexes towards [Cp*Ru(η5-E5)] (E = P, As)","authors":"Maria Haimerl , Manfred Scheer","doi":"10.1080/10426507.2021.2011888","DOIUrl":null,"url":null,"abstract":"<div><p>The reactivity of the nacnac Cu(I) compound [L<sup>2</sup>Cu(MeCN)] (<strong>2</strong>) (L<sup>2</sup> = [{N(C<sub>6</sub>H<sub>3</sub>Me<sub>2</sub>-2,6)C(Me)}<sub>2</sub>CH]<sup>-</sup>) towards complexes containing aromatic <em>cyclo</em>-E<sub>5</sub> ligands (E = P, As) was investigated. The copper complex was reacted with [Cp*Ru(η<sup>5</sup>-E<sub>5</sub>)] (E = P (<strong>1a-Ru</strong>), As (<strong>1b-Ru</strong>)), yielding the heterometallic complexes [(Cp*Ru)(μ,η<sup>5:2</sup>-E<sub>5</sub>)(L<sup>2</sup>Cu)] (E = P (<strong>3a</strong>), As (<strong>3b</strong>)). These neutral and molecular complexes represent rare examples of the coordination of group 11 metal complexes to <em>cyclo</em>-E<sub>n</sub> units and are also rare examples of the coordination compounds of <strong>1a-Ru</strong> and <strong>1b-Ru</strong>. They were fully characterized by crystallographic and spectroscopic methods and compared to related compounds.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"197 5","pages":"Pages 393-397"},"PeriodicalIF":1.6000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650722011650","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The reactivity of the nacnac Cu(I) compound [L2Cu(MeCN)] (2) (L2 = [{N(C6H3Me2-2,6)C(Me)}2CH]-) towards complexes containing aromatic cyclo-E5 ligands (E = P, As) was investigated. The copper complex was reacted with [Cp*Ru(η5-E5)] (E = P (1a-Ru), As (1b-Ru)), yielding the heterometallic complexes [(Cp*Ru)(μ,η5:2-E5)(L2Cu)] (E = P (3a), As (3b)). These neutral and molecular complexes represent rare examples of the coordination of group 11 metal complexes to cyclo-En units and are also rare examples of the coordination compounds of 1a-Ru and 1b-Ru. They were fully characterized by crystallographic and spectroscopic methods and compared to related compounds.
Cu(I) nacnac配合物对[Cp*Ru(η - 5- e5)] (E = P, As)的反应性
摘要研究了nacnac Cu(I)化合物[L2Cu(MeCN)] (2) (L2 = [{N(c6h3me2 -2,6)C(Me)}2CH]-)对含芳环- e5配体(E = P, As)配合物的反应性。铜配合物与[Cp*Ru(η5-E5)] (E = P (1a-Ru)， As (1b-Ru))反应，生成异金属配合物[(Cp*Ru)(μ，η5:2-E5)(L2Cu)] (E = P (3a)， As (3b))。这些中性和分子配合物是11族金属配合物与环- en单位配位的罕见例子，也是1a-Ru和1b-Ru配位化合物的罕见例子。用晶体学和光谱方法对它们进行了充分的表征，并与相关化合物进行了比较。图形抽象
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Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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