{"title":"Reactivity of Cu(I) nacnac complexes towards [Cp*Ru(η5-E5)] (E = P, As)","authors":"Maria Haimerl , Manfred Scheer","doi":"10.1080/10426507.2021.2011888","DOIUrl":null,"url":null,"abstract":"<div><p>The reactivity of the nacnac Cu(I) compound [L<sup>2</sup>Cu(MeCN)] (<strong>2</strong>) (L<sup>2</sup> = [{N(C<sub>6</sub>H<sub>3</sub>Me<sub>2</sub>-2,6)C(Me)}<sub>2</sub>CH]<sup>-</sup>) towards complexes containing aromatic <em>cyclo</em>-E<sub>5</sub> ligands (E = P, As) was investigated. The copper complex was reacted with [Cp*Ru(η<sup>5</sup>-E<sub>5</sub>)] (E = P (<strong>1a-Ru</strong>), As (<strong>1b-Ru</strong>)), yielding the heterometallic complexes [(Cp*Ru)(μ,η<sup>5:2</sup>-E<sub>5</sub>)(L<sup>2</sup>Cu)] (E = P (<strong>3a</strong>), As (<strong>3b</strong>)). These neutral and molecular complexes represent rare examples of the coordination of group 11 metal complexes to <em>cyclo</em>-E<sub>n</sub> units and are also rare examples of the coordination compounds of <strong>1a-Ru</strong> and <strong>1b-Ru</strong>. They were fully characterized by crystallographic and spectroscopic methods and compared to related compounds.</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650722011650","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The reactivity of the nacnac Cu(I) compound [L2Cu(MeCN)] (2) (L2 = [{N(C6H3Me2-2,6)C(Me)}2CH]-) towards complexes containing aromatic cyclo-E5 ligands (E = P, As) was investigated. The copper complex was reacted with [Cp*Ru(η5-E5)] (E = P (1a-Ru), As (1b-Ru)), yielding the heterometallic complexes [(Cp*Ru)(μ,η5:2-E5)(L2Cu)] (E = P (3a), As (3b)). These neutral and molecular complexes represent rare examples of the coordination of group 11 metal complexes to cyclo-En units and are also rare examples of the coordination compounds of 1a-Ru and 1b-Ru. They were fully characterized by crystallographic and spectroscopic methods and compared to related compounds.
Cu(I) nacnac配合物对[Cp*Ru(η - 5- e5)] (E = P, As)的反应性
摘要研究了nacnac Cu(I)化合物[L2Cu(MeCN)] (2) (L2 = [{N(c6h3me2 -2,6)C(Me)}2CH]-)对含芳环- e5配体(E = P, As)配合物的反应性。铜配合物与[Cp*Ru(η5-E5)] (E = P (1a-Ru)， As (1b-Ru))反应，生成异金属配合物[(Cp*Ru)(μ，η5:2-E5)(L2Cu)] (E = P (3a)， As (3b))。这些中性和分子配合物是11族金属配合物与环- en单位配位的罕见例子，也是1a-Ru和1b-Ru配位化合物的罕见例子。用晶体学和光谱方法对它们进行了充分的表征，并与相关化合物进行了比较。图形抽象
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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