Flexible Lead-Free Na0.5bi0.5tio3-Eutio3 Solid Solution Film Capacitors with Stable and Superior Energy Storage Performances

Fei Guo, Zhifeng Shi, Bo Yang, Yaping Liu, Shifeng Zhao
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Abstract

Flexible lead-free Na0.5Bi0.5TiO3-EuTiO3 solid solution film capacitors were fabricated. The recoverable energy storage density and energy storage efficiency reach 65.4 J/cm3 and 52 %, respectively, due to the great insulation characteristic and relaxor behaviors. And the energy storage performances for the flexible solid solution films show excellent stabilities on temperature, frequency and bending endurance, especially, with bending endurance stability over 105 cycles. The flexoelectric effect also contributes to the regulation on energy storage performances by bending the flexible films. This work provides an candidate for the flexible film capacitors with giant application potentials in wearable energy storage devices.
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具有稳定优异储能性能的柔性无铅Na0.5bi0.5tio3-Eutio3固溶体薄膜电容器
制备了柔性无铅Na0.5Bi0.5TiO3-EuTiO3固溶体薄膜电容器。由于具有良好的绝缘特性和弛豫特性,可回收储能密度和储能效率分别达到65.4 J/cm3和52%。柔性固溶体薄膜的储能性能在温度、频率和弯曲耐久性方面表现出优异的稳定性,特别是在105次循环以上的弯曲耐久性稳定性。挠性电效应还通过弯曲柔性薄膜来调节储能性能。这项工作为柔性薄膜电容器在可穿戴储能设备中具有巨大的应用潜力提供了一种候选材料。
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