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Anomalous Growth of Dislocation Density in Titanium During Recovery 钛中位错密度在恢复过程中的异常增长
Pub Date : 2023-06-01 DOI: 10.2139/ssrn.3931609
I. Ivanov, J. J. G. Moreno, K. Emurlaev, D. Lazurenko, I. Bataev
It is generally believed, that the dislocation density in cold-worked metals decreases during recovery. Here, we used in-situ synchrotron X-ray diffraction to show that the dislocation density in [[EQUATION]] -titanium increases at the initial stages of heating. Under conditions of low dislocation mobility, the generation of new dislocation decreases the overall level of stresses in the deformed material. This phenomenon was clearly confirmed by classical molecular dynamics simulations. The dislocation reactions and dislocations dynamics were considered in detail.
一般认为,在恢复过程中,冷加工金属中的位错密度减小。在这里,我们使用原位同步加速器x射线衍射表明,在加热的初始阶段,[[EQUATION]] -钛中的位错密度增加。在位错迁移率较低的条件下,新位错的产生降低了变形材料中的整体应力水平。经典分子动力学模拟清楚地证实了这一现象。详细讨论了位错反应和位错动力学。
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引用次数: 1
Mixing Entropy Threshold for Entropy-Tailored Materials 熵裁剪材料的混合熵阈值
Pub Date : 2022-03-01 DOI: 10.2139/ssrn.3897764
Jie Wang, Yu-ling Tang, Shun Li, Zhouran Zhang, Y. Ye, Li'an Zhu, S. Bai
To determine the effect of mixing entropy on multicomponent alloys and to find the mixing entropy threshold for entropy-tailored materials, including high-entropy alloys and medium-entropy alloys, the microstructure and mechanical properties of 23 Ti-Zr-Nb-V alloys were investigated. The Laves phase content of Ti-Zr-Nb-V alloys was obtained using image recognition technology . According to the component threshold for Laves phases and HCP phase disappearance, V(Nb)-Zr(Ti) pseudo-binary phase diagrams, which can predict the phases of ternary Ti-Zr-V and Zr-Nb-V alloys, were established. By comparing the Laves phase content in Ti-Zr-Nb-V alloys obtained from experimental statistics, pseudo-binary phase diagrams and thermodynamic calculations, the Δ S mix threshold for entropy-tailored materials was 1.10~1.21R. The dependence of the yield strength and fracture strain of the Ti-Zr-Nb-V alloys further reveals that the mechanical properties of entropy-tailored alloys are essentially controlled.
为了确定混合熵对多组分合金的影响,并找出高熵合金和中熵合金的混合熵阈值,研究了23种Ti-Zr-Nb-V合金的显微组织和力学性能。采用图像识别技术测定了Ti-Zr-Nb-V合金的Laves相含量。根据Laves相和HCP相消失的分量阈值,建立了可以预测Ti-Zr-V和Zr-Nb-V三元合金相的V(Nb)-Zr(Ti)伪二元相图。通过对比实验统计、拟二元相图和热力学计算得到的Ti-Zr-Nb-V合金的Laves相含量,可以得出:熵定制材料的Δ S混合阈值为1.10~1.21R。Ti-Zr-Nb-V合金屈服强度与断裂应变的相关性进一步表明,熵定制合金的力学性能基本上是可控的。
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引用次数: 4
Comparative Study of Stress and Strain Partitioning Behaviors in Medium Manganese and Transformation-Induced Plasticity-Aided Bainitic Ferrite Steels 中锰与相变诱导塑性辅助贝氏体铁素体钢应力应变分配行为的比较研究
Pub Date : 2022-03-01 DOI: 10.2139/ssrn.3918921
Tomohiko Hojo, M. Koyama, Bakuya Kumai, Y. Shibayama, A. Shiro, T. Shobu, H. Saitoh, Saya Ajito, E. Akiyama
The origins of the superior work hardening capability of medium manganese (M-Mn) and conventional transformation-induced plasticity-aided bainitic ferrite (TBF) steels of similar tensile strength and elongation are comparatively investigated via synchrotron X-ray diffraction measurements. The M-Mn steel undergoes preferential plastic deformation in austenite; its superior work hardening capability and associated uniform elongation are attributed to the high rates of martensitic transformation and dislocation accumulation per strain in the retained austenite. By contrast, the excellent work hardening behavior and uniform elongation of the TBF steel are attributed to the sustained transformability until the occurrence of a large strain and significant stress partitioning between the face-centered cubic (FCC) and body-centered cubic (BCC) phases due to the high austenite phase stability and high resistance to slip deformation of austenite.
通过同步x射线衍射测量,对比研究了具有相似抗拉强度和延伸率的中锰(M-Mn)钢和传统相变诱导塑性辅助贝氏体铁素体(TBF)钢优异加工硬化性能的原因。M-Mn钢在奥氏体中发生优先塑性变形;其优越的加工硬化能力和相关的均匀伸长率归因于马氏体转变和每应变中保留的奥氏体中位错积累的高速率。相比之下,TBF钢优异的加工硬化行为和均匀伸长率归因于高奥氏体相稳定性和高抗滑移变形能力,在大应变和面心立方相(FCC)和体心立方相(BCC)之间发生显著的应力分配之前具有持续的可变形性。
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引用次数: 7
The 3-D Aboav-Weaire Relation From Modified Mean-Field Model 修正平均场模型的三维上维关系
Pub Date : 2022-02-01 DOI: 10.2139/ssrn.3927819
Yue Li, Zhijun Wang, Junjie Li, Jincheng Wang
Grain-environment heterogeneity has been known to play a vital role in grain growth kinetics. In general, the topological correlation between grains and first nearest neighbors is described by the famous Aboav-Weaire law. However, its predictions in 3-D normal grain growth do not exactly match the experiments and simulations. In this work, with an approximation of the MacPherson-Srolovitz law, an alternative approach of the A-W relation is developed from the modified mean-field model. The predictions are not only significantly closer to the reality, but also successfully reflects the effect of grain-environment heterogeneity on the normalized grain growth rate.
晶粒-环境异质性在晶粒生长动力学中起着至关重要的作用。一般来说,晶粒和第一近邻之间的拓扑关系由著名的Aboav-Weaire定律描述。然而,它对三维正常晶粒生长的预测并不完全符合实验和模拟。在这项工作中,与MacPherson-Srolovitz定律近似,从修正的平均场模型发展了A-W关系的另一种方法。预测结果不仅明显接近实际,而且成功地反映了籽粒-环境异质性对归一化籽粒生长速率的影响。
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引用次数: 1
Metallurgical Joining of Immiscible System: Pure Mg and Pure Fe 非混相体系的冶金连接:纯Mg和纯Fe
Pub Date : 2022-02-01 DOI: 10.2139/ssrn.3949512
H. Das, B. Gwalani, Xiaolong Ma, P. Upadhyay
Understanding the metallurgical joinability of pure Mg and pure Fe and their interfacial microstructure lays the foundation for deciphering the complicated mechanism of joining various magnesium alloys and steels in applications. Pure Mg and pure Fe were successfully joined to form a metallurgical bond for the first time using the friction stir assisted scribe technique. Through detailed characterization, we found that the two immiscible metals are bonded by a critical interfacial oxide layer that spans only ~40 ± 10 nm. We present the first direct experimental evidence of the presence of a Mg/Fe oxide rich interfacial layer using high-resolution electron microscopy and discuss the contribution of oxide formation toward a successful joining mechanism.
了解纯镁和纯铁的冶金接合性及其界面微观结构,是破解各种镁合金和钢在实际应用中的复杂接合机理的基础。利用搅拌摩擦辅助划线技术,首次成功地将纯Mg和纯Fe连接在一起形成了冶金键。通过详细的表征,我们发现这两种不混溶的金属由一个临界界面氧化层结合,该氧化层的跨度仅为~40±10 nm。我们使用高分辨率电子显微镜首次提出了富Mg/Fe氧化物界面层存在的直接实验证据,并讨论了氧化物形成对成功连接机制的贡献。
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引用次数: 3
Tuning the Perpendicular Magnetic Anisotropy in Co/Pt Multilayers Grown by Facing Target Sputtering and Conventional Sputtering 面向目标溅射和常规溅射生长Co/Pt多层膜中垂直磁各向异性的调节
Pub Date : 2022-01-01 DOI: 10.2139/ssrn.3891420
O. Yıldırım, M. Marioni, C. Falub, H. Rohrmann, D. Jaeger, Marco Rechsteiner, D. Schneider, H. Hug
Magnetic properties of [Co(0.4 nm)/Pt(0.7 nm)]5 multilayers are tailored by controlling the sputtering voltage during the growth of cobalt layers by a facing target cathode. It is shown that increasing sputtering voltage up to 150 V leads to an improved crystalline texture and this results in larger magnetic anisotropies and out-of-plane coercive fields. At a higher cathode voltage of 540 V however crystalline texture quality slightly worsens and this is accompanied by a decrease in the effective anisotropy. Using facing target cathode sputtering, the crystalline structure of the multilayers can be controlled without applying any heat treatment and this can be used to optimize the magnetic properties of Co/Pt multilayers for specific applications.
通过对钴层生长过程中的溅射电压进行控制,对[Co(0.4 nm)/Pt(0.7 nm)]5多层膜的磁性进行了调整。结果表明,当溅射电压达到150 V时,晶体结构得到改善,磁各向异性和面外矫顽场增大。然而,在较高的阴极电压(540 V)下,晶体织构质量略有恶化,这伴随着有效各向异性的降低。利用面向目标阴极溅射,多层材料的晶体结构可以在不进行任何热处理的情况下控制,这可以用于优化特定应用的Co/Pt多层材料的磁性能。
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引用次数: 4
Martensitic Transformation Mechanism of Mg-Sc Lightweight Shape Memory Alloys Mg-Sc轻量化形状记忆合金马氏体相变机理研究
Pub Date : 2022-01-01 DOI: 10.2139/ssrn.3881302
Wenbin Zhao, Kun Zhang, E. Guo, Lei Zhao, X. Tian, Chang-long Tan
Abstract Mg-Sc alloys are known as novel and promising lightweight shape memory alloys (LWSMAs), which have outstanding performance. Yet, a precise understanding of the microscopic picture and interactions governing the martensitic transformation (MT) remains elusive. We systematically investigate the MT of Mg-Sc alloys using first-principles methods. The result of generalized solid-state nudged elastic band methods confirms that no energy barrier inhibits the MT. We show that the bcc structure of Mg26Sc6 is dynamical instability at 0 K caused by electron-phonon coupling and Fermi surface nesting. Particularly, the high-temperature stability of Mg26Sc6 is revealed for the first time using the temperature-dependent effective potential method. The softening of the acoustic mode at Γ-R corresponds to two neighboring (1 0 1) planes moving towards each other, and forms martensite phase. Our calculations provide the complete and atomic-level mechanism for the MT of Mg-Sc alloys and shed some light on the design of new LWSMAs.
摘要Mg-Sc合金是一种具有优异性能的新型轻量化形状记忆合金。然而,对微观图像和控制马氏体相变(MT)的相互作用的精确理解仍然是难以捉摸的。本文采用第一性原理方法系统地研究了Mg-Sc合金的MT。广义固体轻推弹性带方法的结果证实了没有能量势垒抑制MT。我们证明了Mg26Sc6的bcc结构在0 K时是由电子-声子耦合和费米表面嵌套引起的动态不稳定性。特别是,利用温度相关有效电位法首次揭示了Mg26Sc6的高温稳定性。声波模式在Γ-R处的软化对应于相邻的两个(1 0 1)平面相互移动,形成马氏体相。我们的计算提供了Mg-Sc合金MT的完整的原子水平机制,并为新型lwsma的设计提供了一些启示。
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引用次数: 7
Self-Formation of Dual Glassy-Crystalline Structure in Magnetron Sputtered W–Zr Films 磁控溅射W-Zr薄膜中双玻璃晶结构的自形成
Pub Date : 2021-05-01 DOI: 10.2139/ssrn.3721835
P. Zeman, S. Haviar, M. Červená
Abstract Self-formation of a unique dual glassy-crystalline structure in binary W–Zr system was observed for a film with 28 at.% Zr prepared by magnetron co-sputtering. The film is composed of conical columnar domains of α-W(Zr) solid solution structure surrounded by featureless areas corresponding to a W–Zr metallic glass. The conical domains have their axes perpendicular to the film surface. Most of the domains have the apex at or close to the substrate surface, which corresponds to the point of primary nucleation. The surface ratio of glassy and crystalline phase (bases of the cones) is dependent on the film thickness. The dual structure is prepared in a very narrow window of the elemental composition. We suppose that the specific elemental composition and the diffusivity or mobility of sputtered adatoms are crucial for the self-formation of the dual structure.
摘要:在28 at的二元W-Zr体系中,观察到一种独特的双玻璃晶结构自形成。磁控共溅射制备% Zr。该薄膜由α-W(Zr)固溶体结构的圆锥形柱状畴组成,其周围无特征区与W-Zr金属玻璃相对应。圆锥域的轴垂直于薄膜表面。大多数结构域的顶端在底物表面或靠近底物表面,这与初成核点相对应。玻璃相和结晶相(锥体的基底)的表面比例取决于薄膜的厚度。二元结构是在元素组成的一个非常窄的窗口中制备的。我们认为,特定的元素组成和溅射原子的扩散率或迁移率对二元结构的自形成至关重要。
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引用次数: 4
Remelting Induced Fully-Equiaxed Microstructures with Anomalous Eutectics in the Additive Manufactured Ni 32Co 30Cr 10Fe 10Al 18 Eutectic High-Entropy Alloy 增材制造的Ni 32Co 30Cr 10Fe 10Al 18共晶高熵合金重熔诱导具有异常共晶的全等轴组织
Pub Date : 2021-03-15 DOI: 10.2139/ssrn.3805157
Kexuan Zhou, Junjie Li, Qingfeng Wu, Zhilin Zhang, Zhijun Wang, Jincheng Wang
Large columnar grains with epitaxial growth are commonly obtained in the additive manufacturing of metals, resulting in anisotropic mechanical properties and even hot-tearing cracks. Here, we demonstrate a new approach via remelting-introduced columnar-to-equiaxed transformation to promote the formation of fully-equiaxed microstructures in the additive manufacturing of Ni32Co30Cr10Fe10Al18 eutectic high-entropy alloy. Our present work displays promising isotropic mechanical properties with a superior combination of strength and ductility, compared to conventional as-cast and other as-printed eutectic high-entropy alloys. This novel finding could be applicable to the additive manufacturing of other eutectic systems for equiaxed microstructure control and performance optimization.
在金属增材制造中,通常会得到外延生长的大柱状晶粒,从而导致各向异性的力学性能,甚至产生热撕裂裂纹。在此,我们展示了一种新的方法,通过引入重熔的柱向等轴转变来促进Ni32Co30Cr10Fe10Al18共晶高熵合金增材制造中全等轴组织的形成。与传统的铸造和其他印刷共晶高熵合金相比,我们目前的工作显示出有希望的各向同性力学性能,具有优越的强度和延展性。这一新发现可应用于其他共晶体系的增材制造,用于等轴组织控制和性能优化。
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引用次数: 2
Simultaneously Enhanced Strength-Ductility of AlCoCrFeNi 2.1 Eutectic High-Entropy Alloy via Additive Manufacturing 增材制造同时增强AlCoCrFeNi 2.1共晶高熵合金的强度-塑性
Pub Date : 2021-02-01 DOI: 10.2139/ssrn.3777625
Liufei Huang, Yao Sun, N. Chen, Hengwei Luan, G. Le, Xue Liu, Yaqi Ji, Yiping Lu, P. Liaw, Xiaoshan Yang, Yuzhao Zhou, Jin-Feng Li
The negative effects of thermal cycles in the process of additive manufacture present a challenge for the control of microstructure so as to fabricate the products with improved properties compared to cast. In this work, AlCoCrFeNi2.1 eutectic high entropy alloy (EHEA) was prepared by laser metal deposition (LMD). Comparison with the cast samples, the LMD-fabricated EHEA showed significantly enhanced tensile strength (by 19.7%) and increased tensile ductility (by 56.4%). Such enhancement in mechanical properties owing to the refinement of the uniformly distributed eutectic-structure, which was composed of a ductile FCC(L12) phase and a strong BCC(B2) phase embedded with a high density of nano-precipitates. These nano-precipitates effectively pinned the dislocations, resulting strain hardening/dislocation accumulation capability. The present work provides a new strategy to utilize both the high cooling rates of LMD and the eutectic-structure characteristics for achieving homogeneous structures and superior mechanical properties to those prepared by traditional processing techniques.
增材制造过程中热循环的负面影响对组织的控制提出了挑战,从而使产品的性能优于铸件。采用激光金属沉积(LMD)法制备了AlCoCrFeNi2.1共晶高熵合金(EHEA)。与铸造样品相比,lmd制备的EHEA抗拉强度显著提高(提高19.7%),拉伸塑性显著提高(提高56.4%)。这种力学性能的增强是由于均匀分布的共晶结构的细化,该共晶结构由韧性FCC(L12)相和强BCC(B2)相组成,其中嵌入了高密度的纳米析出物。这些纳米沉淀物有效地固定了位错,导致了应变硬化/位错积累能力。本研究为利用LMD的高冷却速度和共晶组织特性来获得均匀的组织和优于传统加工技术的力学性能提供了一种新的策略。
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引用次数: 3
期刊
AMI: Scripta Materialia
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