Thermodynamic properties of 2-methyl-5-phenylfuran-3-carboxylic

R. R. Kostiuk, Y. Horak, N. Velychkivska, I. Sobechko, D. B. Pyshna, V. Dibrivnyi
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Abstract

The temperature dependence of the saturated vapor pressure and the combustion energy of 2-methyl-5-phenylfuran-3-carboxylic acid were determined by experimental methods. Based on the obtained data, the values of the enthalpies of combustion and formation in the condensed state were calculated. The enthalpy of sublimation was recalculated to 298K. The additive Benson scheme is supplemented with new fragments for calculating the enthalpies of formation in the gaseous state. The possibility of using the Joback method to calculate the enthalpies of formation of aryl furans in the gaseous state is analyzed.
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2-甲基-5-苯基呋喃-3-羧酸的热力学性质
用实验方法测定了2-甲基-5-苯基呋喃-3-羧酸的饱和蒸气压和燃烧能与温度的关系。根据得到的数据,计算了缩合态的燃烧焓和生成焓。重新计算升华焓为298K。加性Benson格式补充了新的片段,用于计算气态的生成焓。分析了用Joback法计算芳基呋喃气态生成焓的可能性。
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