Preparation, Spectroscopic, Bioactive and Theoretical Studies of Mixed Ligand Complexes

A. A. Al-Hamdani, Nawres Khalid Gabraael Al-dulyme, S. Ahmed, H. M. Basheer
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引用次数: 2

Abstract

The mixed ligands complexes of 8-hydroxyquinoline and Schiff base 1, 5-dimethyl-4-(5oxohexan-2-ylideneamino)-2-phenyl-1H-pyrazol-3 (2H)-one (L) with Cr (III) , Mn (II) , Fe (II) , Co (II) , Ni (II) , Cu (II) and Zn (II) ions were prepared. The compounds have been characterized by NMR, FT-IR, UV-Vis and mass spectra, elemental microanalysis (C.H.N.), magnetic moment, chloride contain, atomic absorption and molar conductance. All prepared complexes were octahedral geometry. Compound structures treated theoretically using the program hyper chem. 8 in gas phase at 298°K. The compounds were also screened for their bioactive property such as antifungal and antibacterial. [DOI: 10.22401/JUNS.20.3.09]
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混合配体配合物的制备、光谱、生物活性和理论研究
制备了8-羟基喹啉与希夫碱1,5 -二甲基-4-(5氧己烷-2-基氨基)-2-苯基- 1h -吡唑-3 (2H)- 1 (L)与Cr (III)、Mn (II)、Fe (II)、Co (II)、Ni (II)、Cu (II)和Zn (II)离子的混合配体配合物。通过NMR、FT-IR、UV-Vis和质谱、元素微量分析、磁矩、氯含量、原子吸收和摩尔电导等手段对化合物进行了表征。所制备的配合物均为八面体结构。用超化学程序对化合物结构进行了理论处理。在298°K的气相中。并对化合物的抗真菌、抗菌等生物活性进行了筛选。(DOI: 10.22401 / JUNS.20.3.09)
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