ELECTROCHEMICAL TREATMENT OF AIRPORT RUNOFF WATER CONTAINING ETHYLENE GLYCOL

D.Sh. Magomedova, Z.M. Alimirzayeva, A. Magomedova, A. Isaev, T. Kharlamova
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Abstract

Airports are one of the sources of environmental pollution with runoff water containing emerging contaminants. The process of electrochemical purification of model runoff water containing ethylene glycol and formed during the treatment of aircraft with anti-icing agents was studied. As an anode there was used PbO2 electrode. The structure and morphology of PbO2 electrode samples obtained by electrochemical deposition on the titanium plate surface was studied using scanning electron microscopy. It revealed that the use of PbO2 as an anode makes it possible to bring the COD value of the solution to the required standards. After electrolysis, the COD values for all studied ethylene glycol concentrations from 10 to 100 mg/l were in the range of 0.34-4.6 mgO2/l. The effect of current density, concentration of ethylene glycol and sodium chloride on the efficiency of electrochemical oxidation of ethylene glycol was analyzed.
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含乙二醇机场径流水的电化学处理
机场是环境污染的来源之一,径流中含有新出现的污染物。研究了飞机防冰剂处理过程中产生的含乙二醇模型径流水的电化学净化过程。采用PbO2电极作为阳极。利用扫描电镜研究了电化学沉积法制备的PbO2电极样品在钛板表面的结构和形貌。结果表明,使用PbO2作为阳极可以使溶液的COD值达到要求的标准。电解后,在10 ~ 100 mg/l的乙二醇浓度范围内,COD值在0.34 ~ 4.6 mgO2/l之间。分析了电流密度、乙二醇浓度和氯化钠浓度对乙二醇电化学氧化效率的影响。
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