Ultrasound Assisted Production of Metal Foam From Polyurethane Precursor

Asima Zahoor, A. Mourad
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Abstract

Metal foam is a novel class of metals that is inspired by naturally occurring, functionally graded, cellular structures like wood and bones. The properties of metal foam are so diverse that they can be tailored to suit the particular need, hence the study of metal foams has become attractive to researchers and efforts are being made to optimize the methodology to develop the metal foam. Most of the production methods cannot be widely utilized because of difficult process control and high production costs. One of the most economical ways to produce metal foam is adopting conventional electro deposition technique. The electro deposition technique starts from first metalizing the non-conducting polymeric foam and then electrically depositing metal onto this metallized precursor foam with open cells and later the precursor is removed by the sintering process. The main hindrance in this process is that foam being multi layered, a uniform deposition of the metal in the inner layers of the foam was not achieved. After sintering it was found that the foam sample turned out hollow at the center, due to lack or very less deposition of the metal. Experiments aiming to overcome this problem of non-uniform deposition of the metal in the inner layers of the precursor were conducted. It was found that mechanical agitation in the form of low frequency ultrasound promoted the uniform electro deposition throughout the metalized multilayered precursor. Finally, desired strength foam was produced.
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超声辅助聚氨酯前驱体制备金属泡沫
金属泡沫是一类新型金属,其灵感来自于自然发生的、功能分级的细胞结构,如木材和骨头。金属泡沫的性质是如此的多样化,以至于它们可以根据特定的需要进行定制,因此金属泡沫的研究已经成为研究人员的吸引力,并且正在努力优化开发金属泡沫的方法。大多数生产方法由于过程控制困难、生产成本高而不能广泛应用。采用传统的电沉积技术是制备金属泡沫最经济的方法之一。电沉积技术首先将非导电聚合物泡沫金属化,然后将金属电沉积在具有开口孔的金属化前驱体泡沫上,然后通过烧结过程去除前驱体。该工艺的主要障碍是泡沫是多层的,金属在泡沫内层的均匀沉积是无法实现的。烧结后发现,由于缺乏或很少沉积金属,泡沫样品在中心出现空心。为了克服金属在前驱体内层不均匀沉积的问题,进行了实验。研究发现,低频超声形式的机械搅拌促进了多层金属化前驱体的均匀电沉积。最后得到了要求强度的泡沫。
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