Evaluation of US/UV/SO40‒ Advanced Oxidation Process on the Removal of Amoxicillin from Aqueous Solutions

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Abstract

Introduction: Pharmaceuticals, especially antibiotics, are new contaminants that have created a major environmental concern because of their cumulative nature, adverse effects, and drug resistance. Their existence in domestic wastewater will pollute water resources. This study aimed to determine the performance of US/UV/SO40‒ processes in the removal of Amoxicillin (AMX). Method: The current experimental study used ultrasonic waves (US), ultraviolet rays (UV), and sulfate radicals (SO40‒). To detect the effect of variables, including contact time (0-120 min), the antibiotic concentration (5-50 mg/l), pH (3-9), persulfate concentration (1-7 mM), and the input power (550 W), the reactor has been sampled in different intervals, and the residue concentration was detected using a spectrophotometer in 294 nm length wave. Results: The results showed that the separate use of US and UV had no high operation with the best removal percentages of 33.3% and 13.29%, respectively. Simultaneous use of US/UV/SO40‒ showed a more high reduction in AMX concentration and the best removal percentage was 94.12% that took place in pH=6, the antibiotic concentration of 5 mg/L, persulfate concentration of 5 mM, and contact time of 120 min. Conclusion: The result showed that the US/UV/SO40‒ process can be used as an operational process to remove the AMX from an aqueous environment.
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US/UV/SO40 -深度氧化法去除水溶液中阿莫西林的效果评价
药物,特别是抗生素,是一种新的污染物,由于其累积性、副作用和耐药性,已经造成了主要的环境问题。它们在生活废水中的存在会对水资源造成污染。本研究旨在确定US/UV/SO40 -工艺去除阿莫西林(AMX)的性能。方法:本实验采用超声波(US)、紫外线(UV)和硫酸根(SO40 -)。为检测接触时间(0 ~ 120 min)、抗生素浓度(5 ~ 50 mg/l)、pH(3 ~ 9)、过硫酸盐浓度(1 ~ 7 mM)、输入功率(550 W)等因素对反应釜的影响,采用分光光度计在294 nm波长波长下检测残留浓度。结果:紫外分光光度法和紫外分光光度法分离使用效果不佳,最佳去除率分别为33.3%和13.29%。同时使用US/UV/SO40 -对AMX的去除率较高,在pH=6、抗生素浓度为5 mg/L、过硫酸盐浓度为5 mM、接触时间为120 min时,其去除率为94.12%。结论:US/UV/SO40 -工艺可作为去除水中环境中AMX的操作工艺。
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