The Role of Filler Interface in Suppressing the Erosion of Silicone Rubber Under DC Voltage

Alhaytham Alqudsi, R. Ghunem, É. David, Y. Hadjadj
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Abstract

The presented paper aims to highlight the role of fillerpolymer interface on the DC erosion resistance of silicone rubber (SiR) outdoor insulators. SiR composites filled with nano-sized boron nitride and fumed silica have been prepared in this study. Electrical and thermal experimental tools of the inclined plane tracking-erosion test, simultaneous thermogravimetric-differential thermal analyses, and thermal conductivity measurements are used to analyze the prepared nanocomposites. The analysis primarily investigates whether the composite’s enhancement of thermal conductivity or filler interface would be more influential on erosion suppression. Literature reports that the boron nitride filler improves SiR’s thermal conductivity, whereas fumed silica provides an exceptional interaction with SiR at the filler interface. SiR was filled with boron nitride at 5wt% (percent by weight) and 10wt%, while fumed silica was loaded with 5wt% and used as a reference composite in the study. The obtained results clearly indicate a superior erosion resistance of the silica filled SiR over the boron nitride filled one. An observation which seemingly could give more significant role of the filler-polymer interface on the erosion resistance of SiR used for high voltage DC outdoor insulators.
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填料界面在抑制直流电压下硅橡胶腐蚀中的作用
研究了填料-聚合物界面对硅橡胶室外绝缘子抗直流侵蚀性能的影响。本研究制备了以纳米氮化硼和气相二氧化硅填充的SiR复合材料。采用斜面跟踪-侵蚀试验、同步热重-差热分析和导热系数测量等电学和热实验工具对制备的纳米复合材料进行了分析。分析主要探讨了复合材料的热导率增强和填料界面增强孰优孰劣。文献报道,氮化硼填料提高了SiR的导热性,而气相二氧化硅在填料界面上提供了与SiR的特殊相互作用。SiR分别以5wt%(重量百分比)和10wt%填充氮化硼,而气相二氧化硅则以5wt%填充,作为研究中的参考复合材料。所得结果清楚地表明二氧化硅填充的SiR比氮化硼填充的SiR具有更好的抗侵蚀性能。这一观察结果似乎可以说明填料-聚合物界面对高压直流室外绝缘子用SiR的耐冲蚀性能有更重要的作用。
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