Synthesis and Characterization of Nickel (II), Cobalt (II), Copper (ll) and Zinc (II) Complexes with 5-Chloropyridine-2-Carbaldehydethiosemicarbazone

Mohammed Adam Adam Abdelbary, Mohammed Sulieman Ali Eltoum, Elmugdad Ahmed Ali
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Abstract

5-chloropyridine-2-carbaldehydethiosemicarbazone (HL1) and its nickel(II), cobalt(II), Zinc(II) and copper(II) complexes: [Ni(HL1)2], [Co(HL1)2], [Zn(HL1)2], [Cu(HL1)2], [Cu(HL1)], were synthesized and characterized. The ligand has been characterized by elemental analyses, IR, 1H NMR and Mass spectroscopy. The dentate nature of the ligand is evident from the spectral obtained data and literature.
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镍(II)、钴(II)、铜(ll)和锌(II)配合物与5-氯吡啶-2-乙醛代硫代氨基脲的合成与表征
合成了5-氯吡啶-2-乙醛代硫代氨基脲(HL1)及其镍(II)、钴(II)、锌(II)、铜(II)配合物:[Ni(HL1)2]、[Co(HL1)2]、[Zn(HL1)2]、[Cu(HL1)2]、[Cu(HL1)]。通过元素分析、IR、1H NMR和质谱对该配体进行了表征。从光谱获得的数据和文献中可以明显看出配体的齿状性质。
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