Influence of At-Bridge Nitro Groups on the Photophysics and Chiroptics of helicoBODIPYs: A Step Forward towards the Development of New Chiroptical Sensors
César Ray, Carolina Díaz-Norambuena, C. Schad, Florencio Moreno, A. R. Agarrabeitia, M. Ortiz, T. Arbeloa, J. Bañuelos, B. L. Maroto, S. D. L. Moya
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Abstract
: A new helicoBODIPY (bisBODIPY with helical chirality) with nitro groups at the chiral bridge has been synthesized as a model to study the influence of the at-bridge substitution on the photophysics and chiroptics of the helicoBODIPY. This preliminary study reveals that at-bridge substitution can be a strategy for the development of chiroptical sensors based on helicoBODIPYs.
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