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American social media on the Russia-Ukraine war: A multimodal analysis 美国社交媒体对俄乌战争的多模态分析
Pub Date : 2022-12-30 DOI: 10.26565/2218-2926-2022-25-05
I. Shevchenko
This research focuses on political narrative about the Russia-Ukraine war in American social media. It aims to investigate the type and configuration of multimodal semiotic resources used to present the events of this war and shape their perception by the audience, primarily American; The New York Times Telegram channel coverage of the 2022 Russian invasion as a case study. What kind of semiotic resources do American social media deploy to construct the narrative about the war? What are the dominant post formats, how they deploy information about the Russia-Ukraine war and construe its perception: the concepts of the war, of Ukraine as a victim of aggression and a fighter for independence, of Russia as a terrorist-state, and of their allies and opponents? Theoretically, this study is underpinned by a cognitive-semiotic, political linguistic and multimodal approach. In political media narrative, storytelling shapes perception of war realities: it frames and reframes the readers’ construal of the world, ascribes connotations to facts and events. A multimodal narrative involves different semiotic resources—verbal, graphic, audial, and cinematographic (in video). The configuration of these heterogeneous signs in a particular Telegram channel’s post defines its influence as predominantly rational or emotional. The findings show that the following post formats are typical for The New York Times Telegram channel: image followed by text and link to another site (the most frequent); gallery (a gallery of images) and quote (a quotation with its source/author as the title) (less frequent); video and audio (rarely used). They serve to accentuate, elaborate, and extend the information in the post. I argue that Telegram posts together with users’ emoji-reactions are a specific interactive genre of a multimodal political discourse. Emojis realize both pragmatic and cognitive functions: on the one hand, they are effective instruments to measure users’ reaction; on the other, they contribute to meaning-making by evaluating and making salient the concepts described. The dominance of rational and verified information in The New York Times Telegram channel creates the true image of Russia’s genocidal war against Ukraine and provides a fair assessment of related concepts.
本研究主要关注美国社交媒体上关于俄乌战争的政治叙事。它旨在调查用于呈现这场战争事件的多模态符号学资源的类型和配置,并塑造观众(主要是美国人)的感知;《纽约时报》电报频道对2022年俄罗斯入侵的报道作为案例研究。美国社交媒体运用了什么样的符号学资源来构建关于战争的叙事?主要的帖子格式是什么?他们如何部署有关俄乌战争的信息,并解释其看法:战争的概念,乌克兰是侵略的受害者和争取独立的斗士,俄罗斯是恐怖主义国家,以及他们的盟友和对手?理论上,本研究以认知符号学、政治语言学和多模态方法为基础。在政治媒体叙事中,讲故事塑造了人们对战争现实的看法:它构建和重塑了读者对世界的理解,赋予事实和事件以内涵。多模态叙事涉及不同的符号学资源——语言、图像、听觉和电影(在视频中)。在一个特定的电报频道的帖子中,这些异质标志的配置定义了它的影响主要是理性的或情感的。调查结果显示,以下是《纽约时报》电报频道的典型帖子格式:图片后面跟着文字和另一个网站的链接(最常见);Gallery(图片库)和quote(以来源/作者为标题的引文)(较少使用);视频和音频(很少使用)。它们的作用是强调、阐述和扩展帖子中的信息。我认为Telegram的帖子和用户的表情反应是一种特殊的多模式政治话语的互动类型。表情包实现了语用功能和认知功能:一方面,它是衡量用户反应的有效工具;另一方面,他们通过评价和突出所描述的概念来促进意义的形成。《纽约时报》电报频道(The New York Times Telegram)以理性和经过验证的信息为主导,塑造了俄罗斯对乌克兰进行种族灭绝战争的真实形象,并对相关概念提供了公正的评估。
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引用次数: 1
Sustainable fashion in the English language mirror 可持续时尚在英语语言的镜子
Pub Date : 2022-12-30 DOI: 10.26565/2218-2926-2022-25-01
Alla Belova
The research is conducted in the critical eco-linguistics domain, an umbrella term for diverse academic inquiries and empirical evidence. The aim of the article is the analysis of English words and lexical structures used to verbalize two major aspects of sustainable fashion as a new movement and world vision – ethical fashion and conscious fashion with the focus on animals in fashion and thrifting. Sustainable fashion has a number of dimensions categorized as conscious, green, and circular, eco-friendly fashion, ethical fashion, vegan fashion. The goal of conscious fashion has much in common with environmentalism and green marketing. Ethical fashion focuses on exploitation in fashion, of both animals and humans, and encompasses animal rights, fair trade of animal-related products, working conditions in fashion industry what are quite often not decent. Vegan fashion promotes non-animal plant-based textiles and man-made fabrics. Circular fashion centres on clothes recycling, extending terminology to upcycling, downcycling and regenerating. Thrifting, renting, and sharing are to popularize slow fashion and conscious fashion. Coverage of fashion sustainability in mass media resulted into coinage of new eco-conscious words and word collocations and their increasing frequency. Several word-forming models dominate in the sustainable fashion terminology including numerous V-ing words to describe manufacturing processes and activities, non+N, non+Adj coinages to emphasize denial of traditional practices. Some words (animal, cruelty) and word-forming components (eco-) have become more noticeable in sustainable fashion in the past decade. The adjective 'sustainable' is among 1% top words in Modern English (Merriam-Webster dictionary online, n.d.) though the collocation ‘sustainable fashion’ is not fixed yet by this dictionary or its counterparts. Thus sustainable fashion is to be conceptualized to find its way to dictionaries as well as to mentality of fashion designers, clothes manufacturers and consumers worldwide. Increasing vocabulary of sustainable fashion should become more familiar to consumers to push them to rethinking their lifestyle, clothing choices, becoming eco-conscious.
这项研究是在批判生态语言学领域进行的,这是一个涵盖各种学术调查和经验证据的总称。本文的目的是分析英语单词和词汇结构,用来表达可持续时尚作为一种新的运动和世界愿景的两个主要方面-道德时尚和有意识的时尚,重点是时尚和节俭中的动物。可持续时尚有很多维度,包括有意识的、绿色的、循环的、环保的、道德的、素食的时尚。自觉时尚的目标与环保主义和绿色营销有很多共同之处。道德时尚关注的是时尚界对动物和人类的剥削,包括动物权利,动物相关产品的公平贸易,时尚行业的工作条件往往不体面。素食时尚提倡非动物性植物纺织品和人造织物。循环时尚以服装回收为中心,将术语扩展到升级回收、降级回收和再生。节俭、租房、分享是普及慢时尚和自觉时尚。大众媒体对时尚可持续性的报道导致了新的生态意识词汇和词汇搭配的创造和频率的增加。在可持续时尚术语中,有几个词构成模式占主导地位,包括许多描述制造过程和活动的V-ing词,以及强调否认传统做法的non+N, non+Adj的新词。在过去的十年里,一些词(动物,残忍)和构词成分(生态)在可持续时尚中变得更加引人注目。形容词“sustainable”是现代英语中1%的热门词汇之一(韦氏在线词典,n.d),尽管“sustainable fashion”的搭配尚未被该词典或其同类词典确定。因此,可持续时尚应该被概念化,以便在字典中找到它的方式,以及时尚设计师、服装制造商和全球消费者的心态。消费者应该更熟悉可持续时尚的词汇,促使他们重新思考自己的生活方式、服装选择,变得有环保意识。
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引用次数: 1
Multimodal imagery in picture books for children 儿童绘本中的多模态意象
Pub Date : 2022-12-30 DOI: 10.26565/2218-2926-2022-25-06
A. Tsapiv
This research focuses on revealing visual means of creating imagery in picture books, addressed to a child-reader. The theory of J. Appleyard has been acknowledged. It is believed that in early and later childhood children realize themselves as players, heroes, and heroines of the stories. Given that, visual imagery contributes to their reading experience and creates special world, which attracts child-readers. The theory suggested by G. Kress and T, van Leeuwen, supplemented by C. Painter, J. Martin, and L. Unsworth has been developed and amplified. Social distance, proximity, attitude, and contact in picture books for children are created by means of visual devices, i.e. color and saturation, page layout, close up and long-shot depiction. It is assumed that the most prominent means of creating meanings in picture books for children becomes the focaliser’s viewpoint, as in most narratives for children a child or an anthropomorphic character of a child’s age is a focaliser of the events. It is claimed that close-up depiction of images creates a special eye contact with the reader, as well as color decisions become visual means of creating the point of view of the focaliser. Furthermore, full-length pictures become a visual tool of implementation ironic senses. In ironic narrative for children, the incongruity is shaped via visual depiction of the characters, which builds the contrast between conventional understanding of issues and their representation in narratives for children. Proximity and distance of the images implements social and psychological connection, status or misunderstanding between the characters. Special angle of viewing the images serves as a device of revealing the type of the narrator of the story, as oblique and high angle become a tool of narrating a story by an adult narrator.
本研究的重点是揭示在绘本中创造图像的视觉手段,针对儿童读者。J. Appleyard的理论已经得到了认可。人们认为,在童年的早期和后期,孩子们意识到自己是故事的玩家、英雄和女主角。因此,视觉意象有助于他们的阅读体验,创造了特殊的世界,吸引了儿童读者。G. Kress和T . van Leeuwen提出的理论,由C. Painter, J. Martin和L. Unsworth补充,得到了发展和扩大。儿童绘本中的社交距离、接近度、态度、接触都是通过视觉手段来创造的,比如色彩和饱和度、页面布局、特写和长镜头的描绘。人们认为,在儿童绘本中创造意义的最重要手段是成为焦点者的观点,因为在大多数儿童叙事中,儿童或儿童年龄的拟人化人物是事件的焦点。据称,对图像的特写描绘与读者产生了一种特殊的目光接触,颜色的选择也成为创造聚焦器视角的视觉手段。此外,全长图片成为实现讽刺意义的视觉工具。在儿童反讽叙事中,这种不协调是通过对人物的视觉描绘来塑造的,这在儿童叙事中建立了对问题的传统理解与他们的表现之间的对比。图像的接近和距离实现了人物之间的社会和心理联系,地位或误解。特殊的视角作为揭示故事叙述者类型的手段,斜视角和高视角成为成人叙述者叙事的工具。
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引用次数: 0
Shakespeare’s quotations in German linguoculture: an ecolinguistic approach 德国语言文化中的莎士比亚语录:一种生态语言学方法
Pub Date : 2022-12-30 DOI: 10.26565/2218-2926-2022-25-03
N. Onishchenko, Tetiana Smoliana
The article deals with the features of eptonymized quotations from William Shakespeare in German within the framework of the translingual aspect of the ecolinguistic approach to the study of linguistic and speech phenomena. Ecolinguistics makes it possible to study the existence of language in combination of language and speech units with geopolitical, historical, social, and psychological factors. According to this approach, English is considered “super-heavy” in terms of the number of native speakers, which means it can influence the languages with a lower number of native speakers, such as “heavy” German. The aim of the work is to study the features of this influence on the example of quotations from the works of the most famous British writer of all times, William Shakespeare, which are adapted by German linguoculture and which have their own formal and functional characteristics at the present stage of German language development. German versions of eptonymized Shakespeare quotations are the result of cognitive, historical and socio-cultural factors of adaptation of new symbolic phenomena to the language environment-the receiver. The translingual aspect of ecolinguistics allows to explain the use of eptonymized units of English language and culture in the context and by means of German as a receiving language, where these units acquire specific characteristics. The establishment of these characteristics is the purpose of the presented work, which studies as an object the quotations from the Shakespeare works that have acquired the qualities of winged expressions (eptonymized quotations) on the German ground or even demonstrate a tendency to phraseology. The objectives of the work are to determine the ways in which Shakespeare's quotations fall into German linguoculture, to establish structural and semantic features of the use of eptonymized Shakespeare quotations in modern German internet discourses, to describe the main functions of such Shakespeare quotations in the mentioned discourses, taking into account the creolization factor of the text.Consideration of the socio-historical basis for the integration of Shakespeare's work into German linguoculture allowed us to identify the main factors of popularization of quotations and their penetration into the linguistic consciousness of native German speakers. These factors include translations of Shakespeare's works into German, stage productions, borrowing and processing of Shakespeare's plots by German-speaking writers, and including the works by the British author into mandatory educational programs. According to the formal features, there have been distinguished exact citations in phraseological meaning without pointing to the primary source, exact citations in phraseological meaning with pointing to the primary source, exact citations in phraseological meaning intently without pointing to the source, citation with transformations and unspoken citation without intended transformation. Suc
本文从生态语言学研究语言和言语现象的翻译角度出发,探讨了德语莎士比亚语录的表位化特征。生态语言学将语言和言语单位与地缘政治、历史、社会和心理因素结合起来研究语言的存在。根据这种方法,就以英语为母语的人数而言,英语被认为是“超重”的,这意味着它可以影响以英语为母语的人数较少的语言,比如“重型”德语。本文的目的是研究这种影响对英国最著名的作家威廉·莎士比亚作品的引语的特点,这些引语被德国语言文化改编,在德语发展的现阶段具有自己的形式和功能特征。德文版本的莎士比亚语录是新的符号现象适应语言环境的认知、历史和社会文化因素的结果。生态语言学的翻译方面允许解释英语语言和文化的表位化单位在语境中的使用,并通过德语作为接收语言,这些单位获得了特定的特征。这些特征的建立是本研究的目的,本研究将莎士比亚作品中的引语作为研究对象,这些引语在德国的基础上获得了有翼的表达(符号化引语)的品质,甚至表现出一种短语化的倾向。本研究的目的是确定莎士比亚语录在德语语言文化中的使用方式,建立现代德语网络语篇中使用音节化莎士比亚语录的结构和语义特征,描述这些莎士比亚语录在上述语篇中的主要功能,同时考虑到文本的克里奥尔化因素。考虑到莎士比亚作品融入德国语言文化的社会历史基础,我们可以确定语录普及及其渗透到德语母语者语言意识中的主要因素。这些因素包括将莎士比亚的作品翻译成德语,舞台制作,德语作家借用和处理莎士比亚的情节,以及将英国作家的作品纳入强制性教育课程。根据形式特征,有不指向原始来源的确切引语、指向原始来源的确切引语、不指向原始来源的精确引语、有转换的精确引语和无意图转换的隐性引语。这样的报价具有信息性、装饰性、吸引力和人性化的功能。
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引用次数: 0
Digital discourse in the realm of related phenomena 数字话语领域的相关现象
Pub Date : 2022-12-30 DOI: 10.26565/2218-2926-2022-25-04
A. Prykhodko, N. Lazebna
The article is devoted to the study of digital discourse as the most diverse socio-cultural background of the contemporaries’ interaction. This work outlines the theoretical background of digital-oriented discourse in a harmonious symbiosis with the practical manifestation of its existence. This paper distinguishes between the concepts of “computer discourse”, “virtual discourse” and “digital discourse”. The genres of virtual discourse, such as online learning classes, instant messaging, and video game genres are represented as related, but not equal phenomena. These cutting-edge sociolinguistic phenomena manifest the pragmatic intentions of clients and agents of digital discourse, which are discussed in the matrix of their characteristics. In the key focus of the study, one can find common and distinctive properties of related types of discourse, their parameters, and multilevel means that arrange them. Institutional and institutional-typological characteristics of digital discourse, conditions of communication and ways of its organization are revealed; its socializing and communicative purpose is outlined; hypero- and hyponymic dimensions of discourse are considered; strategies for sending and receiving information are presented; micro-, meso-, and macro-levels of digital discourse are identified; the concept of “digital discourse” is developed.
本文致力于研究数字话语作为当代互动的最多样化的社会文化背景。本文概述了数字化话语在和谐共生中的理论背景及其存在的实践表现。本文对“计算机语篇”、“虚拟语篇”和“数字语篇”的概念进行了区分。虚拟话语的类型,如在线学习课程、即时通讯和视频游戏类型,被表示为相关但不相等的现象。这些前沿的社会语言学现象表明了数字话语的客户和代理人的语用意图,并在其特征矩阵中进行了讨论。在研究的重点中,人们可以发现相关类型话语的共同和独特的属性,它们的参数,以及排列它们的多层次手段。揭示了数字话语的制度性和制度性类型学特征、传播条件和组织方式;概述了它的社交和交际目的;论述的高名和低名维度;提出了信息发送和接收策略;确定了数字话语的微观、中观和宏观层面;提出了“数字话语”的概念。
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引用次数: 0
Strategies of criticism and disapproval in the academic administrative discourse 学术行政话语中的批评与不赞成策略
Pub Date : 2022-12-30 DOI: 10.26565/2218-2926-2022-25-02
N. Molodcha, A. Khilkovska
This article addresses the problem of communicative strategies for conveying criticism and disapproval in statements of appellative genre issued by presidents of American and British top universities. We claim that discursive representation of university chief leaders who are critically evaluating government decisions and incidents forms a linguistic and sociocultural communicative genre system with a set of effective rhetoric and communicative means. In academic administrative discourse, statements of appellative genre are characterized by dynamic application of positive and negative politeness strategies and regular reproduction of value-centered arguments, which update the system of values of the American and British academic communities. Discursive behavior of university chief academic administrators contains the rhetoric that appeals to logic, addressee’s emotions (pathos) and is based on the arguments to ethos, combining this with lexical and stylistic means that ‘threaten’ addressee’ face. Speakers use strategic tautology to increase the significance of the value system of an academic community. The concepts, themes, tasks, and tactical means, identified in the appellative statements of university leaders, contribute to the formation of the concept sphere of American and British academic communities. The results of this present study detail discursive and genre characteristics of the administrative academic discourse and the strategies of conflict (disapproving) discourse in particular. Communicative behavior of university leaders determined, on the one hand, by the value system and, on the other, by strategic aims of communication, can serve as a model of leadership communication and a resource for improving the competence of modern academic leaders.
本文探讨了英美两国顶尖大学校长在申诉文体声明中表达批评和不赞成的交际策略问题。我们认为,批判性地评价政府决策和事件的大学领导的话语表征形成了一套具有有效修辞和交际手段的语言和社会文化交际类型系统。在学术行政话语中,称谓式语句动态运用积极和消极礼貌策略,有规律地再现以价值为中心的论点,更新了美英学术界的价值体系。大学首席学术管理者的话语行为包含诉诸逻辑的修辞,收件人的情感(感伤),并基于对精神的论点,将其与“威胁”收件人的“脸”的词汇和风格手段相结合。演讲者使用战略同义反复来增加学术团体价值体系的重要性。在大学领导的申诉性陈述中确定的概念、主题、任务和策略手段有助于形成美国和英国学术界的概念领域。本研究的结果详细介绍了行政学术话语的话语和类型特征,特别是冲突(不赞成)话语的策略。大学领导的交际行为一方面是由交际的价值体系决定的,另一方面是由交际的战略目标决定的,可以作为领导交际的典范和提高现代学术领袖能力的资源。
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引用次数: 0
Emotive lexicon of the political narrative: Ukraine and the West in Chinese media 政治叙事的情感词汇:中国媒体中的乌克兰与西方
Pub Date : 2022-12-30 DOI: 10.26565/2218-2926-2022-25-07
S. Zhabotynska, Anastasiya Brynko
This study, done within the framework of political and cognitive linguistics, discusses emotively loaded language of political media narratives that serve as the major manipulative tool with which propaganda exerts ideological impact on the public. Among various linguistic devices employed in molding the political narrative, a conspicuous role is played by emotively loaded lexicon that is in focus of this inquiry. It aims to expose the contribution of emotively loaded words into featuring a media image of the war launched by Russia against Ukraine in February, 2022. As a result of ideological confrontation between the adversaries and between their allies, this image, targeting home audiences in Russia and Ukraine, as well as foreign audiences, is framed as either pro-Ukrainian and pro-Russian, with the respective emotive assessments being mostly contrastive. Our study considers a pro-Russian image of the war shaped by the English version of The Global Times popular tabloid that belongs to Chinese state media. The dataset includes the articles depicting the Russia-Ukraine war in the context of international relations. The articles were published during June, 2022, three months after the beginning of Russia’s military assault. In the study, the analysis of emotive lexicon grounds on a cognitive ontology of the RUSSIA-UKRAINE WAR image. Such ontology, defined as event-focused, allows for structuring information about the event proper and its participants. Their verbally crafted ‘portraits’ are made salient through the scope of employed emotive expressions, which facilitates priming and entrenchment of the intended biased image in the reader’s mind.
本研究在政治和认知语言学的框架内完成,讨论了政治媒体叙事中作为宣传对公众施加意识形态影响的主要操纵工具的情感负载语言。在塑造政治叙事的各种语言手段中,充满情感的词汇发挥着突出的作用,这是本文探讨的重点。它的目的是揭露饱含感情的文字对媒体描绘2022年2月俄罗斯对乌克兰发动的战争的影响。由于对手和盟友之间在意识形态上的对抗,这种针对俄罗斯和乌克兰国内观众以及外国观众的形象,要么是亲乌克兰的,要么是亲俄罗斯的,而各自的情感评估大多是截然不同的。我们的研究考虑了中国官方媒体旗下广受欢迎的小报《环球时报》英文版塑造的亲俄战争形象。该数据集包括在国际关系背景下描述俄乌战争的文章。这些文章发表于2022年6月,也就是俄罗斯开始军事进攻的三个月后。在本研究中,情感词汇的分析以俄乌战争形象的认知本体论为基础。这种本体被定义为以事件为中心,允许结构化关于事件本身及其参与者的信息。他们口头上精心制作的“肖像”通过使用的情感表达范围变得突出,这有助于在读者脑海中启动和巩固有意的偏见形象。
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引用次数: 0
Radziszewski-Type Oxidation of 3,5-di(α-cyanostyryl)-1,2,4-thiadiazoles radziszewski型氧化3,5-二(α-氰苯基)-1,2,4-噻二唑
Pub Date : 2022-10-31 DOI: 10.3390/ecsoc-25-11790
P. Dahno, A. G. Levchenko, V. Dotsenko
: Due to the presence of two acrylonitrile fragments, 3,5-di( α -cyanostyryl)-1,2,4-thiadiazoles are prone to react under Radziszewski reaction conditions (oxidative hydrolysis of nitriles to amides) with the simultaneous epoxidation and formation of epoxyamides. We found that the reaction proceeds in a non-selective way and yields a mixture of products of regioisomeric oxidation. Only in one case we succeeded to isolate the product of double epoxidation. The structure of the epoxyamides products was confirmed by IR and NMR spectroscopy data. Abstract: Due to the presence of two acrylonitrile fragments, 3,5-di(α-cyanostyryl)-1,2,4-thiadia-zoles are prone to react under Radziszewski reaction conditions (oxidative hydrolysis of nitriles to amides) with the simultaneous epoxidation and formation of epoxyamides. We found that the reaction proceeds in a non-selective way and yields a mixture of products of regioisomeric oxidation. Only in one case we succeeded to isolate the product of double epoxidation. The structure of the epoxyamides products was confirmed by IR and NMR spectroscopy data. funding V.V.D.
由于两个丙烯腈片段的存在,3,5-二(α -氰苯基)-1,2,4-噻二唑在Radziszewski反应条件下(腈氧化水解成酰胺)容易发生反应,同时环氧化生成环氧酰胺。我们发现该反应以非选择性的方式进行,并产生区域异构体氧化产物的混合物。只有一种情况下,我们成功地分离了双环氧化产物。产物的结构经红外光谱和核磁共振谱证实。摘要:由于两个丙烯腈片段的存在,3,5-二(α-氰苯基)-1,2,4-噻二唑容易在Radziszewski反应条件下(腈氧化水解成酰胺)发生反应,同时发生环氧化反应并生成环氧酰胺。我们发现该反应以非选择性的方式进行,并产生区域异构体氧化产物的混合物。只有一种情况下,我们成功地分离了双环氧化产物。产物的结构经红外光谱和核磁共振谱证实。资金V.V.D.
{"title":"Radziszewski-Type Oxidation of 3,5-di(α-cyanostyryl)-1,2,4-thiadiazoles","authors":"P. Dahno, A. G. Levchenko, V. Dotsenko","doi":"10.3390/ecsoc-25-11790","DOIUrl":"https://doi.org/10.3390/ecsoc-25-11790","url":null,"abstract":": Due to the presence of two acrylonitrile fragments, 3,5-di( α -cyanostyryl)-1,2,4-thiadiazoles are prone to react under Radziszewski reaction conditions (oxidative hydrolysis of nitriles to amides) with the simultaneous epoxidation and formation of epoxyamides. We found that the reaction proceeds in a non-selective way and yields a mixture of products of regioisomeric oxidation. Only in one case we succeeded to isolate the product of double epoxidation. The structure of the epoxyamides products was confirmed by IR and NMR spectroscopy data. Abstract: Due to the presence of two acrylonitrile fragments, 3,5-di(α-cyanostyryl)-1,2,4-thiadia-zoles are prone to react under Radziszewski reaction conditions (oxidative hydrolysis of nitriles to amides) with the simultaneous epoxidation and formation of epoxyamides. We found that the reaction proceeds in a non-selective way and yields a mixture of products of regioisomeric oxidation. Only in one case we succeeded to isolate the product of double epoxidation. The structure of the epoxyamides products was confirmed by IR and NMR spectroscopy data. funding V.V.D.","PeriodicalId":11441,"journal":{"name":"ECSOC-25","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91382028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Characterization of a Water-Soluble Pentamethine Indocyanine Dye for Peptide Labeling 肽标记用水溶性五甲基吲哚菁染料的合成与表征
Pub Date : 2022-07-18 DOI: 10.3390/ecsoc-25-11768
Cátia D. F. Martins, M. Raposo, S. Costa
: A water-soluble pentamethine cyanine dye was synthesized for further conjugation with peptides. The dye preparation was accomplished by solution-phase chemistry and the synthesized compounds were characterized by the usual techniques (nuclear magnetic resonance, UV-vis absorption and fluorescence spectroscopies and mass spectrometry). The photophysical properties of cyanine 4 were studied in aqueous media, namely in phosphate-buffered saline (PBS) at pH 7.4. Sulfo-Cy5 carboxylic acid 4 exhibited a narrow absorption band and a high molar extinction coefficient (log ε = 5.11) at 646 nm. The wavelength of maximum fluorescence was found in the near-infrared (NIR) region at 661 nm. Therefore, due to its excellent spectral proprieties, good water solubility and emission in the NIR region, dye 4 can be employed in the synthesis of fluorescence resonance energy transfer (FRET) probes for studying enzymatic hydrolysis in vitro.
合成了一种水溶性五胺菁染料,用于与多肽的进一步偶联。染料的制备采用液相化学方法完成,合成的化合物采用核磁共振、紫外-可见吸收、荧光光谱和质谱等常用技术进行表征。研究了花青素4在pH为7.4的磷酸盐缓冲盐水(PBS)水溶液中的光物理性质。巯基羧酸4在646 nm处具有较窄的吸收带和较高的摩尔消光系数(log ε = 5.11)。在近红外(NIR)区发现最大荧光波长为661 nm。因此,由于染料4具有优异的光谱特性、良好的水溶性和近红外发射特性,可用于合成荧光共振能量转移(FRET)探针,用于体外酶解研究。
{"title":"Synthesis and Characterization of a Water-Soluble Pentamethine Indocyanine Dye for Peptide Labeling","authors":"Cátia D. F. Martins, M. Raposo, S. Costa","doi":"10.3390/ecsoc-25-11768","DOIUrl":"https://doi.org/10.3390/ecsoc-25-11768","url":null,"abstract":": A water-soluble pentamethine cyanine dye was synthesized for further conjugation with peptides. The dye preparation was accomplished by solution-phase chemistry and the synthesized compounds were characterized by the usual techniques (nuclear magnetic resonance, UV-vis absorption and fluorescence spectroscopies and mass spectrometry). The photophysical properties of cyanine 4 were studied in aqueous media, namely in phosphate-buffered saline (PBS) at pH 7.4. Sulfo-Cy5 carboxylic acid 4 exhibited a narrow absorption band and a high molar extinction coefficient (log ε = 5.11) at 646 nm. The wavelength of maximum fluorescence was found in the near-infrared (NIR) region at 661 nm. Therefore, due to its excellent spectral proprieties, good water solubility and emission in the NIR region, dye 4 can be employed in the synthesis of fluorescence resonance energy transfer (FRET) probes for studying enzymatic hydrolysis in vitro.","PeriodicalId":11441,"journal":{"name":"ECSOC-25","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89844739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Anion Colorimetric Chemosensor Based on a Benzimidazole-Functionalized BODIPY Derivative 基于苯并咪唑功能化BODIPY衍生物的阴离子比色化学传感器
Pub Date : 2022-07-18 DOI: 10.3390/ecsoc-25-11754
R. Gonçalves, Sónia C. S. Pinto, S. Costa, M. Raposo
: A BODIPY derivative bearing a benzimidazole unit at position 2 and an electron donor group (anthracene) at the meso position was synthetized and characterized by the usual spectroscopic techniques. The evaluation of the compound as a colorimetric chemosensor was performed in solutions of acetonitrile/water (75:25) in the presence of several anions (HSO 4 − , NO 3 − , H 2 PO 4 − , CN − , BzO − , ClO 4 − , Br − , F − , I − and CH 3 CO 2 − ) with biomedical and environmental relevance. The investigated BODIPY derivative demonstrated a selective color change from pink to yellow upon interaction with a hydrogen sulfate anion (HSO 4 − ).
合成了一种具有2位苯并咪唑和中间位给电子基团(蒽)的BODIPY衍生物,并用通常的光谱技术对其进行了表征。在具有生物医学和环境相关性的阴离子(hso4−、no3−、h2po4−、CN−、BzO−、clo4−、Br−、F−、I−和ch3co 2−)存在的乙腈/水(75:25)溶液中,对该化合物作为比色化学传感器进行了评价。所研究的BODIPY衍生物在与硫酸氢阴离子(hso4 -)相互作用时显示出从粉红色到黄色的选择性颜色变化。
{"title":"Anion Colorimetric Chemosensor Based on a Benzimidazole-Functionalized BODIPY Derivative","authors":"R. Gonçalves, Sónia C. S. Pinto, S. Costa, M. Raposo","doi":"10.3390/ecsoc-25-11754","DOIUrl":"https://doi.org/10.3390/ecsoc-25-11754","url":null,"abstract":": A BODIPY derivative bearing a benzimidazole unit at position 2 and an electron donor group (anthracene) at the meso position was synthetized and characterized by the usual spectroscopic techniques. The evaluation of the compound as a colorimetric chemosensor was performed in solutions of acetonitrile/water (75:25) in the presence of several anions (HSO 4 − , NO 3 − , H 2 PO 4 − , CN − , BzO − , ClO 4 − , Br − , F − , I − and CH 3 CO 2 − ) with biomedical and environmental relevance. The investigated BODIPY derivative demonstrated a selective color change from pink to yellow upon interaction with a hydrogen sulfate anion (HSO 4 − ).","PeriodicalId":11441,"journal":{"name":"ECSOC-25","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89755109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
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ECSOC-25
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