{"title":"Photolytic Behavior of Silver Iodide1","authors":"G. Burley","doi":"10.6028/jres.067A.032","DOIUrl":null,"url":null,"abstract":"Silver iodide exposed to high intensity radiation in the visible light spectrum was found to yield a powder X-ray diffraction pattern showing marked deviations from ideality. It was found possible to correlate these with a decrease in primary extinction, indicating a constant progress from an ideal to a mosaic type crystallinity. Large single crystals showed pronounced asterism in transmission Laue photographs under similar experimental conditions. Small amounts of colloidal silver were detected. A mechanism for this process in silver iodide is proposed, in general agreement with the theory of the photographic process. The primary difference from the other silver halides appears to be a considerably slower rate, permitting the observation of a two step process in detail.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"52 1","pages":"301 - 307"},"PeriodicalIF":0.0000,"publicationDate":"1963-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"10","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.6028/jres.067A.032","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 10
Abstract
Silver iodide exposed to high intensity radiation in the visible light spectrum was found to yield a powder X-ray diffraction pattern showing marked deviations from ideality. It was found possible to correlate these with a decrease in primary extinction, indicating a constant progress from an ideal to a mosaic type crystallinity. Large single crystals showed pronounced asterism in transmission Laue photographs under similar experimental conditions. Small amounts of colloidal silver were detected. A mechanism for this process in silver iodide is proposed, in general agreement with the theory of the photographic process. The primary difference from the other silver halides appears to be a considerably slower rate, permitting the observation of a two step process in detail.
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