Solubility isotherms of hydroxyapatite, Ca5(PO4)3OH (OHAp), prepared by titrating a boiling aqueous suspension of Ca(OH)2 with 0.5 M H3PO4, were determined in the ternary system Ca(OH)2–H3PO4–H2O at 5, 15, 25, and 37 °C in the pH range 3.7–6.7 by equilibration with dilute H3PO4 solutions. The solubility product Ks, determined as a function of temperature by a generalized least-squares procedure from 41 experimental points, is given by the equation logKs=−8219.41/T−1.6657−0.098215T.The values of Ks and its dispersion at 25 and 37 °C are 3.04 (0.25) and 2.35 (0.27) × 10−59. There is a maximum in Ks near 16 °C, which may be due to the form of temperature dependence found earlier for the stability constants of the ion pairs CaH2PO4+ and CaHPO40. The relative positions of the isotherms show that OHAp has a negative thermal coefficient of solubility. Thermodynamic functions for the dissolution of the salt are reported. The solubility data previously reported by others for OHAp at 25 °C were reviewed. The solubility products obtained by three of these investigators were comparable with our value of 3.0 × 10−59; their data were reevaluated by the method described here. We conclude that the best value for the solubility product at 25 °C is 4.7 (2.0) × 10−59.
{"title":"Solubility of Ca5(PO4)3OH in the System Ca(OH)2-H3PO4-H2O at 5, 15, 25, and 37 °C","authors":"H. McDowell, T. M. Gregory, W. E. Brown","doi":"10.6028/jres.081A.017","DOIUrl":"https://doi.org/10.6028/jres.081A.017","url":null,"abstract":"Solubility isotherms of hydroxyapatite, Ca5(PO4)3OH (OHAp), prepared by titrating a boiling aqueous suspension of Ca(OH)2 with 0.5 M H3PO4, were determined in the ternary system Ca(OH)2–H3PO4–H2O at 5, 15, 25, and 37 °C in the pH range 3.7–6.7 by equilibration with dilute H3PO4 solutions. The solubility product Ks, determined as a function of temperature by a generalized least-squares procedure from 41 experimental points, is given by the equation logKs=−8219.41/T−1.6657−0.098215T.The values of Ks and its dispersion at 25 and 37 °C are 3.04 (0.25) and 2.35 (0.27) × 10−59. There is a maximum in Ks near 16 °C, which may be due to the form of temperature dependence found earlier for the stability constants of the ion pairs CaH2PO4+ and CaHPO40. The relative positions of the isotherms show that OHAp has a negative thermal coefficient of solubility. Thermodynamic functions for the dissolution of the salt are reported. The solubility data previously reported by others for OHAp at 25 °C were reviewed. The solubility products obtained by three of these investigators were comparable with our value of 3.0 × 10−59; their data were reevaluated by the method described here. We conclude that the best value for the solubility product at 25 °C is 4.7 (2.0) × 10−59.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"112 1","pages":"273 - 281"},"PeriodicalIF":0.0,"publicationDate":"1977-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87911570","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Simultaneous measurements are described of specific heat capacity, electrical resistivity and hemispherical total emittance of the ternary alloy 90Ti-Al-4V in the temperature range 1450 to 1900 K, and the melting point and and the radiance temperature at the melting point of the alloy by a subsecond duration transient technique. The results are expressed by the relations: cp=1.3833−9.943×10−4T+3.745×10−7T2ρ=152.65+1.9304×10−2T−3.9548×10−6T2where cp is in J · g−1 · K−1, ρ is in μΩ · cm, and T is in K. The value of the hemispherical total emittance is 0.39 in the range 1700 to 1900 K. The melting point and the radiance temperature at the melting point are 1943 and 1796 total emittance of the ternary alloy 90Ti-6Al-4V in the temperature range 1450 to 1900 K, and the melting point 0.395. Estimated inaccuracies of measured properties are: 3 percent for specific heat capacity, 1 percent for electrical resistivity, 5 percent for hemispherical total emittance and 8 K for melting point and radiance temperature at the melting point.
{"title":"Thermophysical Measurements on 90Ti-6AI-4V Alloy Above 1450 K Using a Transient (Subsecond) Technique","authors":"A. Cezairliyan, J. McClure, R. Taylor","doi":"10.6028/jres.081A.014","DOIUrl":"https://doi.org/10.6028/jres.081A.014","url":null,"abstract":"Simultaneous measurements are described of specific heat capacity, electrical resistivity and hemispherical total emittance of the ternary alloy 90Ti-Al-4V in the temperature range 1450 to 1900 K, and the melting point and and the radiance temperature at the melting point of the alloy by a subsecond duration transient technique. The results are expressed by the relations: cp=1.3833−9.943×10−4T+3.745×10−7T2ρ=152.65+1.9304×10−2T−3.9548×10−6T2where cp is in J · g−1 · K−1, ρ is in μΩ · cm, and T is in K. The value of the hemispherical total emittance is 0.39 in the range 1700 to 1900 K. The melting point and the radiance temperature at the melting point are 1943 and 1796 total emittance of the ternary alloy 90Ti-6Al-4V in the temperature range 1450 to 1900 K, and the melting point 0.395. Estimated inaccuracies of measured properties are: 3 percent for specific heat capacity, 1 percent for electrical resistivity, 5 percent for hemispherical total emittance and 8 K for melting point and radiance temperature at the melting point.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"28 1","pages":"251 - 256"},"PeriodicalIF":0.0,"publicationDate":"1977-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84516065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Two idealized models for the preheat stage of liquid droplets are analyzed theoretically. These models contain the effects of transient heat conduction and evaporation. It is assumed that the droplet surface area decreases linearly with time. This assumption necessitates the solution of moving boundary problems. These models, however, do not consider gas-phase mass transport. In the finite-gradient model, the temperatures of both the droplet and surrounding hot gases vary spatially and temporally. In the zero-gradient model the gas temperature varies spatially and temporally but the droplet temperature varies only temporally, i.e., the droplet temperature is spatially uniform. Numerical examples, which require extensive calculations of confluent hypergeometric functions, are presented for typical values of the droplet latent heat and evaporation rate constant. The temperature profiles given by the finite-gradient and zero-gradient models agree to within 20 percent of each other for all cases examined.
{"title":"Evaporation of a Liquid Droplet","authors":"R. Kayser, H. Bennett","doi":"10.6028/jres.081A.015","DOIUrl":"https://doi.org/10.6028/jres.081A.015","url":null,"abstract":"Two idealized models for the preheat stage of liquid droplets are analyzed theoretically. These models contain the effects of transient heat conduction and evaporation. It is assumed that the droplet surface area decreases linearly with time. This assumption necessitates the solution of moving boundary problems. These models, however, do not consider gas-phase mass transport. In the finite-gradient model, the temperatures of both the droplet and surrounding hot gases vary spatially and temporally. In the zero-gradient model the gas temperature varies spatially and temporally but the droplet temperature varies only temporally, i.e., the droplet temperature is spatially uniform. Numerical examples, which require extensive calculations of confluent hypergeometric functions, are presented for typical values of the droplet latent heat and evaporation rate constant. The temperature profiles given by the finite-gradient and zero-gradient models agree to within 20 percent of each other for all cases examined.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"4 1","pages":"257 - 266"},"PeriodicalIF":0.0,"publicationDate":"1977-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89239756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rate coefficients for production of stabilized dimeric parent cations at 295 K have been determined in CH3I, CD3I, CH3I—CD3I mixtures, C2H5I, CH3CD2I, CD3CH2I, and C2D5I. These processes are the most rapid reported for association reactions, the various individual values falling within the limits 0.33 × 10−24 (CH3I) and 10.1 ×10−24 cm6 molecule−2 sec−1 (C2H5I). The temperature dependence of the stabilization coefficients in CH3I and CD3I was also measured over the range 220 ± 3 to 320 ± 1 K, as well as the efficiencies of other third bodies in the stabilization process. The differences observed for the variously labelled analogues are interpreted in terms of vibrational level (energy) depression upon deuteration, which affects the intrinsic lifetime of the collision complex.
{"title":"Isotope Effects in the Association Reactions of Methyl and Ethyl Iodide Cations","authors":"L. W. Sieck","doi":"10.6028/jres.081A.016","DOIUrl":"https://doi.org/10.6028/jres.081A.016","url":null,"abstract":"Rate coefficients for production of stabilized dimeric parent cations at 295 K have been determined in CH3I, CD3I, CH3I—CD3I mixtures, C2H5I, CH3CD2I, CD3CH2I, and C2D5I. These processes are the most rapid reported for association reactions, the various individual values falling within the limits 0.33 × 10−24 (CH3I) and 10.1 ×10−24 cm6 molecule−2 sec−1 (C2H5I). The temperature dependence of the stabilization coefficients in CH3I and CD3I was also measured over the range 220 ± 3 to 320 ± 1 K, as well as the efficiencies of other third bodies in the stabilization process. The differences observed for the variously labelled analogues are interpreted in terms of vibrational level (energy) depression upon deuteration, which affects the intrinsic lifetime of the collision complex.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"5 1","pages":"267 - 271"},"PeriodicalIF":0.0,"publicationDate":"1977-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80098022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Very often a non-solvent diffuses into a glassy polymer with a steep concentration profile proceeding at an almost constant rate v yielding a weight gain proportional to time. Such a diffusion is called type II diffusion in order to distinguish it from the more usual “Fickian” diffusion proceeding without such a constant concentration front and yielding, at least in the beginning, a weight gain proportional to the square root of time. It turns out that the conventional diffusion equation without any special new term but with a diffusion coefficient rapidly increasing with concentration has a series of solutions representing exactly such type II diffusion with v as a completely free parameter which determines the steepness of concentration front. With the usual boundary conditions and infinite medium the diffusion coefficient has to become infinite at the highest penetrant concentration. This case can be considered as an extreme limit which is approached to a high degree in an actual experiment. The finite sample thickness, however, requires only a very large but not an infinite diffusion coefficient. Hence type II diffusion is only a special case of possible diffusion processes compatible with the conventional diffusion equation without any need for new terms if only the diffusion coefficient increases sufficiently fast with penetrant concentration.
{"title":"Diffusion with Discontinuous Swelling","authors":"A. Peterlin","doi":"10.6028/jres.081A.013","DOIUrl":"https://doi.org/10.6028/jres.081A.013","url":null,"abstract":"Very often a non-solvent diffuses into a glassy polymer with a steep concentration profile proceeding at an almost constant rate v yielding a weight gain proportional to time. Such a diffusion is called type II diffusion in order to distinguish it from the more usual “Fickian” diffusion proceeding without such a constant concentration front and yielding, at least in the beginning, a weight gain proportional to the square root of time. It turns out that the conventional diffusion equation without any special new term but with a diffusion coefficient rapidly increasing with concentration has a series of solutions representing exactly such type II diffusion with v as a completely free parameter which determines the steepness of concentration front. With the usual boundary conditions and infinite medium the diffusion coefficient has to become infinite at the highest penetrant concentration. This case can be considered as an extreme limit which is approached to a high degree in an actual experiment. The finite sample thickness, however, requires only a very large but not an infinite diffusion coefficient. Hence type II diffusion is only a special case of possible diffusion processes compatible with the conventional diffusion equation without any need for new terms if only the diffusion coefficient increases sufficiently fast with penetrant concentration.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"52 1","pages":"243 - 250"},"PeriodicalIF":0.0,"publicationDate":"1977-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91052846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A quantitative description is given for the densification process of glasses resulting from glass formation at elevated pressures. Phenomenologieal relations are derived, or justified, which allow estimation of the densification rate κ′ (with respect to formation pressure) from various thermodynamic quantities and glass transition behavior. In addition, the estimation of K′ may be facilitated by the application of the hole theory of Simha and Somcynsky. Using these relations κ′ is estimated, and the results from the different methods are compared for data from 23 different organic polymers with glass transition temperatures ranging from 150 to 455 K. The amount of densification appears to be limited by the apparent convergence of the glass temperature and effective decomposition temperature with increasing pressure. Some estimates of limiting values are presented. Finally, changes of refractive index resulting from densification are estimated from the observed, or predicted, densification rates.
{"title":"Thermodynamics of the Densification Process for Polymer Glasses","authors":"J. McKinney, R. Simha","doi":"10.6028/jres.081A.018","DOIUrl":"https://doi.org/10.6028/jres.081A.018","url":null,"abstract":"A quantitative description is given for the densification process of glasses resulting from glass formation at elevated pressures. Phenomenologieal relations are derived, or justified, which allow estimation of the densification rate κ′ (with respect to formation pressure) from various thermodynamic quantities and glass transition behavior. In addition, the estimation of K′ may be facilitated by the application of the hole theory of Simha and Somcynsky. Using these relations κ′ is estimated, and the results from the different methods are compared for data from 23 different organic polymers with glass transition temperatures ranging from 150 to 455 K. The amount of densification appears to be limited by the apparent convergence of the glass temperature and effective decomposition temperature with increasing pressure. Some estimates of limiting values are presented. Finally, changes of refractive index resulting from densification are estimated from the observed, or predicted, densification rates.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"141 1","pages":"283 - 297"},"PeriodicalIF":0.0,"publicationDate":"1977-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73291036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A new humidity calibration facility which uses the two-pressure principle for generating gas of known humidity has been developed at NBS for calibrating and testing hygrometers. The relative humidity range of the two-pressure humidity generator is 3 to 98 percent for ambient temperatures −60 ° to 80 °C and test chamber pressures 5 to 200 kPa (absolute). This is equivalent to a nominal dew/frost point range of −80 ° to 80 °C. Intercomparison tests were made with the NBS standard gravimetric hygrometer over a portion of the generator’s operating range. The estimated maximum uncertainty (three standard deviations) is 0.2 percent RH for temperatures 0 ° to 80 °C which in units of dew point corresponds to an estimated maximum uncertainty of 0.04 °C for dew points −35 ° to 80 °C.
{"title":"The NBS Two-Pressure Humidity Generator, Mark 2","authors":"S. Hasegawa, J. W. Little","doi":"10.6028/jres.081A.010","DOIUrl":"https://doi.org/10.6028/jres.081A.010","url":null,"abstract":"A new humidity calibration facility which uses the two-pressure principle for generating gas of known humidity has been developed at NBS for calibrating and testing hygrometers. The relative humidity range of the two-pressure humidity generator is 3 to 98 percent for ambient temperatures −60 ° to 80 °C and test chamber pressures 5 to 200 kPa (absolute). This is equivalent to a nominal dew/frost point range of −80 ° to 80 °C. Intercomparison tests were made with the NBS standard gravimetric hygrometer over a portion of the generator’s operating range. The estimated maximum uncertainty (three standard deviations) is 0.2 percent RH for temperatures 0 ° to 80 °C which in units of dew point corresponds to an estimated maximum uncertainty of 0.04 °C for dew points −35 ° to 80 °C.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"22 1","pages":"81 - 88"},"PeriodicalIF":0.0,"publicationDate":"1977-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77342880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The recently obtained complete solution of the simultaneous diagonalization of matrices H A and H in the hydrodynamic diffusion equation has basically changed the diagonal values vp of the symmetric matrix H of hydrodynamic interaction between all the beads of the elastic random coil model of the isolated macromolecule in solution. Since these values enter explicitly the expressions for the intrinsic stress and refractive index tensor in an alternating flow field if based on the concept of internal viscosity of the model one had to recalculate all values obtained formerly by using the then generally accepted erroneous set of vp data. The new vp equal unity independent of p while the old values were larger than 1 for small p and smaller for large p. Hence their too large contributions in the former range are partially compensated by their too small contributions in the latter region. As a consequence in the whole range investigated, between 3 and 300 chain links, the differences in rheological and rheooptical effects are relatively small, up to a factor of 2, although at higher link number the differences tend to grow with the logarithm of this number.
{"title":"Frequency Dependence of Intrinsic Stress and Birefringence Tensor of Bead/Spring Model of Polymer Solutions","authors":"A. Peterlin, J. Fong","doi":"10.6028/jres.081A.012","DOIUrl":"https://doi.org/10.6028/jres.081A.012","url":null,"abstract":"The recently obtained complete solution of the simultaneous diagonalization of matrices H A and H in the hydrodynamic diffusion equation has basically changed the diagonal values vp of the symmetric matrix H of hydrodynamic interaction between all the beads of the elastic random coil model of the isolated macromolecule in solution. Since these values enter explicitly the expressions for the intrinsic stress and refractive index tensor in an alternating flow field if based on the concept of internal viscosity of the model one had to recalculate all values obtained formerly by using the then generally accepted erroneous set of vp data. The new vp equal unity independent of p while the old values were larger than 1 for small p and smaller for large p. Hence their too large contributions in the former range are partially compensated by their too small contributions in the latter region. As a consequence in the whole range investigated, between 3 and 300 chain links, the differences in rheological and rheooptical effects are relatively small, up to a factor of 2, although at higher link number the differences tend to grow with the logarithm of this number.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"1 1","pages":"97 - 107"},"PeriodicalIF":0.0,"publicationDate":"1977-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83025519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A line identification band atlas is presented for a 1000 cm−1 segment, from 19 000 to 18 000 cm−1, of the molecular iodine absorption spectrum. Each page of the atlas covers a 20 cm−1 region of the spectrum and contains a CALCOMP produced photodensitometer trace of the spectrum together with accompanying tabular identification data. The tabular data includes: line identification numbers, observed wavenumbers, calculated wavenumbers, and rotational and vibrational assignments.
{"title":"Atlas of the I2 Spectrum from 19 000 to 18 000 cm−1","authors":"J. D. Simmons, J. T. Hougen","doi":"10.6028/JRES.081A.006","DOIUrl":"https://doi.org/10.6028/JRES.081A.006","url":null,"abstract":"A line identification band atlas is presented for a 1000 cm−1 segment, from 19 000 to 18 000 cm−1, of the molecular iodine absorption spectrum. Each page of the atlas covers a 20 cm−1 region of the spectrum and contains a CALCOMP produced photodensitometer trace of the spectrum together with accompanying tabular identification data. The tabular data includes: line identification numbers, observed wavenumbers, calculated wavenumbers, and rotational and vibrational assignments.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"13 1","pages":"25 - 80"},"PeriodicalIF":0.0,"publicationDate":"1977-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84898043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Accurate measurement of stoichiometry of GaAs provides new data which are used for calculation of the atomic weight of Ga. Using the IUPAC accepted value for the atomic weight of As (74.9216), the atomic weight of Ga based on this work is 69.737 ± 0.006. The mean of two independent chemical values for the atomic weight of Ga, one obtained by Lundell and Hoffman and the other in this work, is 69.735.
{"title":"On the Atomic Weight of Gallium","authors":"G. Marinenko","doi":"10.6028/jres.081A.002","DOIUrl":"https://doi.org/10.6028/jres.081A.002","url":null,"abstract":"Accurate measurement of stoichiometry of GaAs provides new data which are used for calculation of the atomic weight of Ga. Using the IUPAC accepted value for the atomic weight of As (74.9216), the atomic weight of Ga based on this work is 69.737 ± 0.006. The mean of two independent chemical values for the atomic weight of Ga, one obtained by Lundell and Hoffman and the other in this work, is 69.735.","PeriodicalId":94340,"journal":{"name":"Journal of research of the National Bureau of Standards. Section A, Physics and chemistry","volume":"18 1","pages":"1 - 4"},"PeriodicalIF":0.0,"publicationDate":"1977-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85898018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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