Fluorine-Containing Siloxane Based Polymer Electrolyte Membranes

O. Mukbaniani, J. Aneli, M. Plonska-Brzezinska, T. Tatrishvili, E. Markarashvili
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Abstract

The hydrosilylation reaction of 2,4,6,8tetrahydro-2,4,6,8-tetramethylcyclotetrasiloxane (D4) with 2,2,3,3-tetrafluoropropyl acrylate and vinyltriethoxysilane in the presence of platinum catalysts (platinum hydrochloric acid, Karstedt’s catalysts and Pt/C (10%) at 323 K) has been carried out and corresponding addition adduct (D4) has been obtained. The synthesized product D4 was analyzed by FT-IR, H, C, and Si NMR spectroscopy. Sol-gel reactions of D4 doped with lithium trifluoromethylsulfonate (triflate) have been studied and solid polymer electrolyte membranes have been obtained. Electric conductivity of solid polymer electrolyte membranes has been determined via electrical impedance spectroscopy.
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含氟硅氧烷基聚合物电解质膜
以2,4,6,8-四氢-2,4,6,8-四甲基环四硅氧烷(D4)为原料,在铂催化剂(铂盐酸、Karstedt催化剂和Pt/C(10%))存在下,在323 K下,与2,2,3,3,3 -四氟丙烯酸丙酯和乙烯基三乙氧基硅烷进行了硅氢化反应,得到了相应的加成物(D4)。对合成产物D4进行了红外光谱、氢、碳和硅核磁共振分析。研究了掺杂三氟甲基磺酸锂的D4的溶胶-凝胶反应,得到了固体聚合物电解质膜。采用电阻抗谱法测定了固体聚合物电解质膜的电导率。
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