F. Palazzetti, A. Lombardi, Shiun-Jr Yang, M. Nakamura, T. Kasai, K. Lin, Dock-Chil Che, Po-Yu Tsai
{"title":"Stereodirectional photodynamics: Experimental and theoretical perspectives","authors":"F. Palazzetti, A. Lombardi, Shiun-Jr Yang, M. Nakamura, T. Kasai, K. Lin, Dock-Chil Che, Po-Yu Tsai","doi":"10.1063/1.4968646","DOIUrl":null,"url":null,"abstract":"Hexapole oriented 2-bromobutane is photodissociated and detected by a slice-ion-imaging technique at 234 nm. The laser wavelength corresponds to the C – Br bond breaking with emission of a Br atom fragment in two accessible fine-structure states: the ground state Br (2P3/2) and the excited state Br (2P1/2), both observable separately by resonance-enhanced multiphoton ionization (REMPI). Orientation is evaluated by time-of-flight measurements combined with slice-ion-imaging.","PeriodicalId":8439,"journal":{"name":"arXiv: Chemical Physics","volume":"70 1","pages":"020020"},"PeriodicalIF":0.0000,"publicationDate":"2016-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"arXiv: Chemical Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/1.4968646","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 7
Abstract
Hexapole oriented 2-bromobutane is photodissociated and detected by a slice-ion-imaging technique at 234 nm. The laser wavelength corresponds to the C – Br bond breaking with emission of a Br atom fragment in two accessible fine-structure states: the ground state Br (2P3/2) and the excited state Br (2P1/2), both observable separately by resonance-enhanced multiphoton ionization (REMPI). Orientation is evaluated by time-of-flight measurements combined with slice-ion-imaging.
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