Determination of phosphorus in different types of waste using the ICP-MS technique

G. Catrina, Lidia Kim, A. Serbanescu, I. Cristea, M. Barbu, I. Nicolescu, G. Vasile
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Abstract

The research aimed to provide an optimized method for the determination of phosphorous concentration in different types of solid waste using inductive coupled plasma mass spectrometry (ICP-MS) technique. The analyzed waste matrices are: a) vegetable waste (P1), b) ash from the incineration of medical waste (P2) c) sewage sludge (P3) and d) sludge from the meat processing industry (P4). The results obtained by the ICP-MS method were compared with the UV-VIS spectrophotometric method for the determination of total phosphorus. In the case of using the colorimetric method by UV-VIS technique, lower results were obtained compared to the ICP-MS method due to the interferences given by the reagents used to determine the total phosphorus. The interferences given by other elements (metals) were also investigated and the performance parameters were determined such as detection limit, quantification limit, recovery and expandend incertainty using ICP-MS technique.
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电感耦合等离子体质谱法测定不同类型废物中的磷
本研究旨在为电感耦合等离子体质谱(ICP-MS)技术测定不同类型固体废物中磷的浓度提供一种优化方法。所分析的废物基质为:a)蔬菜废物(P1), b)医疗废物焚烧产生的灰(P2) c)污水污泥(P3)和d)肉类加工业产生的污泥(P4)。将ICP-MS法与紫外-可见分光光度法测定总磷的结果进行了比较。在使用UV-VIS技术比色法的情况下,由于测定总磷所用试剂的干扰,所得结果低于ICP-MS法。研究了其他元素(金属)的干扰,确定了ICP-MS技术的检出限、定量限、回收率和扩展不确定度等性能参数。
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