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Chemical characterization methods for biodegradable organic wastes with relevance for the composting process. Case study 与堆肥过程相关的可生物降解有机废物的化学表征方法。案例研究
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.218
G. Catrina, Lidia Kim, A. Serbanescu, Georgiana Cernica, C. Bumbac, Marius Sburlis
The study aimed to develop some methods for the compositional characterization of biodegradable waste with relevance to the composting process at the laboratory level. For testing, four waste fractions were selected, such as waste-based on dehydrated sludge, waste from parks (leaves, branches), market waste (mixture of vegetable and fruit), and cardboard waste. For metals and phosphorus, several microwave digestion methods were applied. The ammonium nitrogen content (NH4-N) was determined using a number of extraction procedures (water, CaCl2, and KCl). Three certified reference materials were used for testing the validity of the results. Recovery percentages higher than 90% were obtained. The developed and validated methods are suitable for biodegradable waste characterization used in composting processes.
本研究旨在开发与实验室水平堆肥过程相关的可生物降解废物组成表征的一些方法。为了进行测试,选择了四种废物组分,如脱水污泥废物、公园废物(树叶和树枝)、市场废物(蔬菜和水果的混合物)和纸板废物。对于金属和磷,采用了几种微波消解方法。铵态氮的含量(NH4-N)是通过一些提取程序(水,CaCl2和KCl)来确定的。三种标准物质被用于测试结果的有效性。回收率大于90%。所开发和验证的方法适用于堆肥过程中使用的可生物降解废物的表征。
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引用次数: 0
Options to improve the coagulation process operation in a drinking water treatment plant. Case study 改善饮用水处理厂混凝工艺操作的选择。案例研究
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.214
A. Pacala, Maria Laura Samonid, B. Murariu
Aluminum salts are widely used across Romania in surface water treatment as coagulants. It is well-known that the efficiency of these coagulants has a complex dependency on the nature of the raw water, being affected by temperature, pH, and suspended solids. The objective of this case study was to compare the coagulation-flocculation efficiency process of raw water from the Bega River, at low temperature and turbidity, taking into account the use of alternative coagulating agents such as alum, poly aluminum chloride (PAC), and their mixing in 1:1 ratio. The raw water samples were treated using the "Jar Test" procedure, comparable with the current plant conditions at Timisoara Waterworks and taking into account possible operational improvements. For the mixture method applied in which was combined alum and PAC in 1:1 mixing ratio were achieved lower concentrations in aluminum residual, TOC, and turbidity.
铝盐作为混凝剂在罗马尼亚广泛应用于地表水处理。众所周知,这些混凝剂的效率与原水的性质有复杂的关系,受温度、pH值和悬浮物的影响。本案例研究的目的是比较贝加河原水在低温和低浊度下的混凝-絮凝效果,同时考虑使用明矾、聚氯化铝(PAC)等替代混凝剂,并以1:1的比例混合。原水样品采用“罐子试验”程序处理,与蒂米什瓦拉水厂目前的工厂条件相比较,并考虑到可能的操作改进。采用明矾与PAC以1:1的混合比例混合的混合方法,获得了较低的铝残留量、TOC浓度和浊度。
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引用次数: 0
An overview of methods used for quantification of heavy metal contents in vegetal samples 植物样品中重金属含量定量方法综述
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.201
Gina Vasile Scăețeanu, Rodica Maria Majdar, A. Moț
Continuous monitoring of heavy metals content in vegetal products is a priority for food control and a risk assessment strategy for human health. Having in view the importance of heavy metals surveillance, the aim of this paper is to identify, on the basis of literature data, the most suitable procedures and techniques used for accurate determination of them in vegetal samples. In most cases, quantification of heavy metals in the vegetal matrix is preceded by digestion performed through different protocols chosen carefully because this is a critical step for obtaining accurate results. Among most used techniques for heavy metals’ assessment from vegetal products reported by literature it worth to be mentioned: atomic absorption spectrometry (AAS), inductively coupled plasma-mass spectrometry (ICP-MS), inductively coupled plasma - optical emission spectrometry (ICP-OES), X-ray fluorescence (XRF), neutron activation analysis (NAA), anodic stripping voltammetry (ASV).
持续监测植物产品中的重金属含量是食品控制和人类健康风险评估战略的优先事项。鉴于重金属监测的重要性,本文的目的是在文献资料的基础上,确定用于准确测定植物样品中重金属的最合适的程序和技术。在大多数情况下,在植物基质中重金属的量化之前,要通过精心选择的不同方案进行消化,因为这是获得准确结果的关键步骤。文献报道中最常用的植物产品重金属鉴定技术有:原子吸收光谱法(AAS)、电感耦合等离子体质谱法(ICP-MS)、电感耦合等离子光学发射光谱法(ICP-OES)、x射线荧光法(XRF)、中子活化分析法(NAA)、阳极溶出伏安法(ASV)。
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引用次数: 2
Assessment of environmental pollution level caused by shipbuilding industry 船舶工业环境污染水平评价
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.213
G. Serban, M. Niculescu, V. Iancu, I. Paun, F. Pirvu, Cǎtǎlin Manea, F. Chiriac, G. Vasile
The purpose of the paper was to create databases that would allow a proper assessment of the degree of marine pollution generated by the shipyard industrial sector. The study was conducted over a period of three years, between 2015 and 2017. The parameters determined for the waters collected from the shipyard were within the maximum allowed limits according to the norms in force. However, values very close to the maximum allowable limit were observed in the case of groundwater for nickel, determined from the drilling located near the fuel depot in 2015 and chlorides determined from the drilling located near the galvanizing workshop, both in 2016 and in 2017. The analyzed parameters for the soil samples, collected from various sampling points and different depths, were below the value of the alert thresholds for less sensitive soils, according to Order 756/97. The databases created for this study can contribute as an incipient basis for the development of larger studies that include other industrial sectors as well as a longer evaluation period.
该文件的目的是建立数据库,以便对船厂工业部门造成的海洋污染程度作出适当的评价。该研究在2015年至2017年期间进行了三年。根据现行规范,从船厂收集的水所确定的参数在最大允许范围内。然而,在地下水中镍的值非常接近最大允许限值,这是2015年从燃料库附近的钻探中确定的,以及2016年和2017年从镀锌车间附近的钻探中确定的氯化物。根据第756/97号命令,从不同采样点和不同深度收集的土壤样品的分析参数低于不敏感土壤的警报阈值。为这项研究建立的数据库可以作为发展更大规模研究的初步基础,其中包括其他工业部门和较长的评价期。
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引用次数: 2
Ranking the dietary treatments of broiler chickens in order to reduce nitrogen pollution of the environment 为减少环境氮污染,对肉鸡日粮处理进行排序
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.212
G. Vasile, Anda Tenea, Ecaterina Anca Serban, G. Catrina, V. Badescu, P. A. Vlaicu
The Analytical Hierarchy Process (AHP) methodology was used to rank the tested nutritional solutions and to choose the best nutritional solution in order to reduce environmental pollution with nitrogen. The evaluation methodology consisted in comparing by three evaluators the diets based on the zootechnical performances/thigh meat quality / environmental impact. The diets of tested nutritional solutions were contained either medicinal or aromatic plants (basil, thyme, sage) in a proportion of 1% (batch 2), respectively essential oils (0.05%) of the same plants (batch 1). The application of the AHP methodology indicated that the best nutritional alternative was obtained for basil, either in the form of essential oil or vegetal material.
采用层次分析法(AHP)对试验营养液进行排序,选择最佳营养液,以减少氮对环境的污染。评价方法包括由三名评价员根据动物技术性能/腿肉品质/环境影响对饲粮进行比较。试验营养液的日粮中分别含有1%(第2批)的药用或芳香植物(罗勒、百里香、鼠尾草)和0.05%(第1批)相同植物的精油。AHP方法的应用表明,无论是以精油的形式还是以植物材料的形式,罗勒都是最佳的营养替代品。
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引用次数: 0
Physical-chemical properties of the surface water from shallow lakes of the Matita-Merhei Unit, Danube Delta, Romania: current state and environmental significance 罗马尼亚多瑙河三角洲matta - merhei单元浅水地表水的物理化学性质:现状和环境意义
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.203
I. Catianis, D. Grosu, A. Constantinescu, Laura Tiron Duţu, O. Dobre
This study aimed to assess the water quality of certain lakes (Bogdaproste, Trei Ozere and Radacinos) belonging to the Danube Delta, Romania. Deltaic ecosystems are subject to natural and man-made environmental stressors. If in the past these ecosystems were largely threatened by eutrophication and organic/inorganic pollution, nowadays, we must focus on hydro morphological impact. This refers to the physical character and water content of the aquatic environment, impoundment (dams and flood gate), channelization and embankments, as well as clog/siltation of lakes. Environmental parameters are those physical, chemical and biological indicators used to characterize a freshwater body, and, which vary in time and space. In this regard, 44 water samples were collected in the dry season from the three lakes, for analysis of physical-chemical quality indicators. A series of physical (T, EC, TDS, turbidity, TSS, transparency) and chemical parameters (pH, DO, nutrients, SiO2, TOC, SO42-, ORP, technophilic elements) were considered. The results obtained in the physical-chemical analyses revealed that the majority of parameters were found in line with enforcing environmental regulations. Despite that, P-PO43- and Cd concentration results of some samples were found above certain permissible limits set by the normative. Probably, these inadvertences can be associated with local conditions of the transitional deltaic environment. Further analysis is required conducting repeated measurements with the same question, meaning a routine monitoring, especially P-PO43- and Cd. Finally, it was concluded that the results of this study showed a good quality of water in investigated lakes that did not pose potential health and environmental problems related to the biota.
本研究旨在评价罗马尼亚多瑙河三角洲某些湖泊(博格达普罗斯特、特雷奥泽尔和拉达奇诺斯)的水质。三角洲生态系统受到自然和人为环境压力的影响。如果过去这些生态系统主要受到富营养化和有机/无机污染的威胁,那么现在我们必须关注水文形态的影响。这是指水环境的物理特性和含水量,蓄水(水坝和闸门),渠化和堤防,以及湖泊的堵塞/淤积。环境参数是用来描述淡水水体特征的物理、化学和生物指标,它们随时间和空间而变化。为此,在旱季从三个湖泊中采集了44个水样,进行了理化质量指标分析。考虑了一系列物理参数(T、EC、TDS、浊度、TSS、透明度)和化学参数(pH、DO、营养物、SiO2、TOC、SO42-、ORP、亲技术元素)。理化分析结果显示,大部分参数符合环保法规的要求。尽管如此,部分样品的P-PO43-和Cd浓度结果仍超过了标准规定的允许范围。这些疏忽可能与过渡性三角洲环境的局部条件有关。进一步的分析需要针对同样的问题进行重复测量,即常规监测,特别是P-PO43-和Cd。最后,得出结论,本研究的结果表明,所调查湖泊的水质良好,不会造成与生物群相关的潜在健康和环境问题。
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引用次数: 0
The influence of toxic metals As, Cd, Ni and Pb on nutrients accumulation in Mentha piperita 有毒金属As、Cd、Ni和Pb对薄荷养分积累的影响
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.217
C. Dinu, G. Vasile, Anda Tenea, C. Stoica, S. Gheorghe, Ecaterina Anca Serban
Medicinal plants are, for a considerable part of the population, an important source of treatment for certain diseases. They contain essential nutrients for the human body such as magnesium, iron , and zinc. The present study shows the influence of the addition of As, Cd, Ni, Pb on mineral nutrients in different organs of Mentha piperita. The experiments were carried out in the laboratory for a period of three months (May-July). Mentha piperita plants were AsCd and AsCdNiPb exposed up to final concentrations corresponding to the soil intervention threshold according to Romanian Order no.756/1997 (25 mg/kg As, 5 mg/kg Cd, 150 mg/kg Ni and 100 mg/ kg Pb). Simultaneously with these experiments, a control experiment (M) was performed. To evaluate the effect of the addition of AsCd and AsCdNiPb on the accumulation and transfer of Ca, Cr, Cu, Mn, Mo, Fe and Zn, the transfer coefficient (TC), the translocation factor (TF), and the enrichment factor (EF) were calculated. A higher concentration of Ca, Cr, Cu, Fe, Mn, Mo, and Zn was observed especially in the mint root in the experiments in which AsCdNiPb was added compared to those in which only AsCd was added. The AsCdNiPb addition did not influence the translocation of micro and macronutrients from the root to the aerial (edible) parts of the plant. In the case of the AsCd, addition, the translocation of zinc from the root to the aerial parts (leaves and stem) of the plant was increased.
对相当一部分人来说,药用植物是治疗某些疾病的重要来源。它们含有人体必需的营养物质,如镁、铁和锌。本文研究了添加As、Cd、Ni、Pb对薄荷不同器官矿质营养素的影响。实验在实验室进行,为期3个月(5 - 7月)。根据罗马尼亚法令,薄荷植物AsCd和AsCdNiPb暴露至与土壤干预阈值相对应的最终浓度。756/1997(25毫克/公斤砷,5毫克/公斤镉,150毫克/公斤镍和100毫克/公斤铅)。在进行这些实验的同时,还进行了对照实验(M)。为了评价添加AsCd和AsCdNiPb对Ca、Cr、Cu、Mn、Mo、Fe和Zn的积累和转移的影响,计算了传递系数(TC)、转运因子(TF)和富集因子(EF)。与只添加AsCd的实验相比,添加AsCdNiPb的实验中,薄荷根中Ca、Cr、Cu、Fe、Mn、Mo和Zn的浓度更高。添加AsCdNiPb不影响微量和宏量营养素从根部到植物的气生(可食)部分的转运。此外,在AsCd的情况下,锌从根部转运到植物的地上部分(叶和茎)增加。
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引用次数: 0
In vitro effect of salinity and pH on Fusarium sp., the causal agent of sweet-potato root rot 盐度和pH对甘薯根腐病病原菌镰刀菌的影响
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.205
L. Barbu, Oana Alina Boiu Secoia
Fusarium root rot in a common pathogen of sweet potato, with a wide range of host plants. In the current study six new isolates of Fusarium sp., collected from infected sweet potato plants, along with a reference strain of Fusarium oxysporum, had their growth behavior studied in various pH and saline conditions. In vitro studies showed that salinity higher than 6% NaCl in the PDA substrate significantly reduces the fungal growth. At 12% NaCl, four of seven strains revealed complete mycelia inhibition. However, for the other two isolates, and for the reference strain, 12% salinity only reduced the growth with 77.4%. Regarding the fungal growth at different pH values, it was noticed that tested fusaria were not perturbed at up to 8.5 alkalinity. However, at a pH of 4.5, the growth rate was reduced, although the growth differences were diminished during prolonged incubation time. Considering the in vitro results, saline water should be tested as preventive immersion treatment on the sweet potato sprouts, before their planting, in order to reduce the incidence of Fusarium infection.
根腐病镰刀菌是甘薯常见的病原菌,具有广泛的寄主植物。本研究从感染的甘薯植株中收集了6株新分离的镰刀菌,并研究了一株参比菌株尖孢镰刀菌在不同pH和生理盐水条件下的生长行为。体外研究表明,PDA底物中高于6% NaCl的盐度显著降低了真菌的生长。在12% NaCl处理下,7株菌株中有4株表现出完全的菌丝抑制。而对于其他两株菌株和参考菌株,12%的盐度仅降低了77.4%的生长。对于不同pH值下的真菌生长,注意到在高达8.5的碱度下,被测镰刀菌没有受到干扰。然而,在pH为4.5时,生长速率降低,尽管随着孵育时间的延长,生长差异减小。考虑到离体试验结果,应在红薯芽苗种植前进行盐水预防性浸泡处理试验,以减少镰刀菌感染的发生。
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引用次数: 0
A study regarding the parameters that influence the growth rate of Salix alba 影响白柳生长速率的参数研究
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.210
G. Murariu, R. Enescu, D. Vasile, L. Dincă, G. Mocanu, D. Munteanu
The inventory and evaluation of growth rates for afforested surfaces is extremely important in estimating production levels and in determining the wood quantities that can be harvested. The present research was realized in southeast Romania, on a surface that contains 375h of afforested fields. The monitored surfaces are situated in Hanu-Conachi Independenta Forest, at a relatively low altitude. The study took into account only the surfaces afforested with willow (Salix alba) and extended between 2010 and 2015. The afforested surfaces’ consistency and age were evaluated based on direct observations and measurements. The used numerical analysis on different optimization methods was selected from amongst the most used series from the specialty literature. Our results have shown that evaluations of estimated production growth rates can vary significantly when different statistical analyses and numeric methods are used. By using numerical optimizing models, computer simulations can offer precise estimations regarding growth rates, and consequently, for the efficiency of a given forest inventory. Common numerical interpolation methods or the usage of neuronal networks do not always lead to consistent results. Specific numeric methods are preferable for a better evaluation of growth rates and current inventory. In addition, investments in computer simulation methods and software should be encouraged in order to reach a permanent inventory, improve the efficiency of exploitation operations, and sustain environmental protection.
在估计生产水平和确定可采伐的木材数量方面,对造林表面的生长速度进行清查和评价是极其重要的。目前的研究是在罗马尼亚东南部实现的,在一个包含375小时绿化场地的表面上。监测的地面位于Hanu-Conachi独立森林,海拔相对较低。该研究只考虑了在2010年至2015年间种植了柳树(Salix alba)的地表。通过直接观测和测量,对造林表面的一致性和年龄进行了评价。对不同优化方法的数值分析是从专业文献中最常用的系列中选择的。我们的研究结果表明,当使用不同的统计分析和数值方法时,估计的产量增长率的评估可能会有很大差异。通过使用数值优化模式,计算机模拟可以提供关于生长率的精确估计,从而提供给定森林盘存效率的精确估计。通常的数值插值方法或神经网络的使用并不总是导致一致的结果。为了更好地评估增长率和当前库存,具体的数值方法是可取的。此外,应鼓励对计算机模拟方法和软件进行投资,以便建立永久盘存,提高开采作业的效率,并维持环境保护。
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引用次数: 0
Moving forward sustainable solutions for VOCs biotrickling filtration through co-immobilised microorganisms 通过共固定化微生物推进VOCs生物滴滤的可持续解决方案
Pub Date : 2021-12-17 DOI: 10.21698/rjeec.2021.207
G. Soreanu, M. Diaconu, S. Maier, I. Volf, I. Cretescu
This study is moving forward with some available options for upgrading the biotrickling filters (BTFs) treating volatile organic compounds (VOCs) in air, in the light of lowering their greenhouse gas(GHG) emissions. One of such options refers to the addition of the microalgae component to the biological matrix involved in such systems, by (co)immobilization, for the capture of the carbon dioxide issued from the VOCs biodegradation and potentially contributing to the overall VOCs removal performance. Particularly, alginate beads with (co) immobilized microorganisms (microorganisms isolated from commercial compost and microalgae Arthrospira platensis PCC 8005) are for the first time tested for this purpose, as follows: beads with entrapped compost-based microorganisms and attached microalgae (BTF-I); beads with an entrapped mixture of microalgae and compost-based microorganisms (BTF-II). Although both options provided promising performances in treating air contaminated with ethanol (as a model VOC in this study), the last option exhibited lower CO2 emissions and higher packing bed durability, being more prone to further development and implementation.
这项研究正在推进一些可用的选择,以升级处理空气中挥发性有机化合物(VOCs)的生物滴滤器(BTFs),以降低其温室气体(GHG)的排放。其中一种选择是通过(co)固定化将微藻成分添加到此类系统所涉及的生物基质中,以捕获挥发性有机化合物生物降解产生的二氧化碳,并可能有助于整体去除挥发性有机化合物的性能。特别是,首次为此目的测试了(co)固定化微生物(从商业堆肥和微藻中分离的微生物platarthrospira PCC 8005)的藻酸盐微球,包括:捕获堆肥微生物和附着微藻(BTF-I)的微球;微藻和堆肥微生物(BTF-II)的混合物。虽然这两种选择在处理被乙醇污染的空气(作为本研究中的模型VOC)方面都有很好的表现,但最后一种选择表现出更低的二氧化碳排放和更高的填料床耐久性,更容易进一步开发和实施。
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引用次数: 1
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Romanian Journal of Ecology & Environmental Chemistry
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