Sol-gel auto-combustion synthesis, cation distribution and physicochemical properties of Ni0.6Cd0.4Fe2O4 NPs

B. H. Devmunde, D. P. Nandagawali, M. B. Solunke, D. R. Shengule
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引用次数: 2

Abstract

The intent of begun work is to synthesis and study the structural, electric, magnetic and frequency dependent dielectric properties of Ni0.6Cd0.4Fe2O4 NPs fabricated via sol-gel auto-combustion technic. The XRD data affirmed that the synthesized Ni0.6Cd0.4Fe2O4 NPs do possess a single phase; spinel structure; cubic geometry and ferrite in nature. The lattice constant (a) was estimated to be 8.363 Å and the crystallite size (t) determined from Debay-Scherrer method was found to be 48.70 nm. SEM images of Ni0.6Cd0.4Fe2O4 NPs may propose the spherically shaped with the formation of fusion in gains. Activation energy (∆E) determined from the Arrhenius relation was recorded as 0.03 eV. Eventually, comprehensive magnetic parameters viz. (Ms), (Hc), (nB) were shown to be decreased in comparison to the unloaded NiFe2O4 ferrite as an effect on non-magnetic Cd2+ ions over magnetic Ni2+ and Fe3+ ions.
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Ni0.6Cd0.4Fe2O4 NPs的溶胶-凝胶自燃合成、阳离子分布及理化性质
本文的目的是合成和研究溶胶-凝胶自燃烧法制备的Ni0.6Cd0.4Fe2O4纳米粒子的结构、电、磁和频率相关的介电性能。XRD数据证实合成的Ni0.6Cd0.4Fe2O4 NPs确实具有单相;尖晶石结构;立方几何和自然界中的铁氧体。晶格常数(a)估计为8.363 Å,由Debay-Scherrer法测定的晶粒尺寸(t)为48.70 nm。Ni0.6Cd0.4Fe2O4 NPs的SEM图像显示,随着增益的形成,NPs呈球形。由Arrhenius关系测定的活化能∆E记录为0.03 eV。最后,综合磁性参数(Ms), (Hc), (nB)与未加载的NiFe2O4铁氧体相比,显示出对非磁性Cd2+离子的影响比磁性Ni2+和Fe3+离子的影响要小。
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