Development of polyurethane/polyethylene terephthalate/fiber glass polymeric composite from internal auto parts waste

IF 1.1 4区 材料科学 Q4 MATERIALS SCIENCE, COMPOSITES Progress in Rubber Plastics and Recycling Technology Pub Date : 2022-10-26 DOI:10.1177/14777606221136155
Laura C Fujii, M. Shiino
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Abstract

The use of polymers in the automotive industry has been growing significantly, the recycling of these materials is a major challenge nowadays, since most polymer parts comprises of different types of polymers, and they are joined by chemical adhesives due to their lack of good compatibility. This characteristic hampers the recycling of such polymers, and makes separation economically unfeasible, as a consequence, their final destination has ended up in landfills. In this sense, the present research developed a technique to verify the recyclability of the manufacturing waste polymer auto parts from industry processes, through the polymer layup process to obtain a composite (fiberglass, polyester fiber, polyurethane) in the form of flat panel. To achieve the objectives, the polymers were individually analyzed by differential scanning calorimetry to assist in the definition of the overlap of joined polymers, in which differentiates from the conventional method of polymer blend by extrusion. The preformed polymer was consolidated by a hot press. The polymer composites were evaluated by three-point bending test and their structure was analyzed using scanning electron microscopy (SEM). The results in flexural properties indicate a suitable consolidation strategy when compared with results in literature, which is explained by the presence of glass fiber and PET in the final composition. Through the SEM images, it enabled to observe a good interface between the glass fiber and the polyester-based polymer matrix of the wastes, directly influencing the mechanical results of the material.
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利用汽车内饰件废弃物制备聚氨酯/聚对苯二甲酸乙二醇酯/玻璃纤维聚合物复合材料
聚合物在汽车工业中的使用一直在显着增长,这些材料的回收是当今的主要挑战,因为大多数聚合物部件由不同类型的聚合物组成,并且由于缺乏良好的相容性,它们由化学粘合剂连接。这种特性阻碍了这种聚合物的回收利用,使分离在经济上不可行,因此,它们的最终目的地是垃圾填埋场。从这个意义上说,本研究开发了一种技术来验证工业过程中制造废旧聚合物汽车零部件的可回收性,通过聚合物叠层工艺获得平板形式的复合材料(玻璃纤维,聚酯纤维,聚氨酯)。为了实现目标,通过差示扫描量热法对聚合物进行单独分析,以帮助定义连接聚合物的重叠,这与传统的挤出聚合物共混方法有所不同。预成型的聚合物用热压机固化。采用三点弯曲试验对复合材料进行了表征,并用扫描电镜对复合材料进行了结构分析。与文献结果相比,弯曲性能的结果表明了合适的固结策略,这是由玻璃纤维和PET在最终成分中的存在来解释的。通过SEM图像,可以观察到废料的玻璃纤维与聚酯基聚合物基体之间有良好的界面,直接影响材料的力学效果。
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来源期刊
Progress in Rubber Plastics and Recycling Technology
Progress in Rubber Plastics and Recycling Technology MATERIALS SCIENCE, COMPOSITES-POLYMER SCIENCE
CiteScore
4.40
自引率
7.70%
发文量
18
审稿时长
>12 weeks
期刊介绍: The journal aims to bridge the gap between research and development and the practical and commercial applications of polymers in a wide range of uses. Current developments and likely future trends are reviewed across key areas of the polymer industry, together with existing and potential opportunities for the innovative use of plastic and rubber products.
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