Anticorrosion Activity of 8-Quinoline Sulphonyl Chloride on Mild Steel in 1 M HCl Solution

R. Sundaram, M. Sundaravadivelu
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引用次数: 18

Abstract

An anticorrosion activity of 8-quinoline sulphonyl chloride (8-QSC) on mild steel in 1 M HCl solution was studied by weight loss (WL) method and electrochemical methods, namely, electrochemical impedance spectroscopy (EIS), Tafel polarization (TP), and linear polarization resistance (LPR). Results obtained from WL method, EIS, TP, and LPR, showed that 8-QSC is a good corrosion inhibitor for mild steel in 1 M HCl solution. The results indicated that the inhibition efficiency and extent of surface coverage were increased with increase in inhibitor concentration and decrease in the corrosion rate. This is due to the formation of protective film on the surface of mild steel. Adsorption of 8-QSC on the mild steel surface was found to obey the Langmuir adsorption isotherm. A Tafel plot indicates that the used inhibitor behaves predominantly as cathodic type. The surface morphology of the mild steel was studied by Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray (EDX) Spectroscopy techniques. All the methods give the same order of inhibition efficiencies.
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8-喹啉磺酰氯在1m HCl溶液中对低碳钢的防腐活性
采用失重法(WL)和电化学方法,即电化学阻抗谱法(EIS)、塔菲尔极化法(TP)和线性极化电阻法(LPR)研究了8-喹啉磺酰氯(8-QSC)在1 M盐酸溶液中对低碳钢的防腐性能。WL法、EIS法、TP法和LPR法的结果表明,8-QSC在1 M HCl溶液中是一种较好的低碳钢缓蚀剂。结果表明,随着缓蚀剂浓度的增加和腐蚀速率的降低,缓蚀剂的缓蚀效率和表面覆盖范围增大。这是由于在低碳钢表面形成保护膜。8-QSC在低碳钢表面的吸附服从Langmuir吸附等温线。塔菲尔图表明,所使用的缓蚀剂主要表现为阴极型。利用扫描电镜(SEM)和能量色散x射线(EDX)光谱技术研究了低碳钢的表面形貌。所有方法的抑制效率都是相同的。
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