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Retracted: Inhibition Effect of Substituted Thiadiazoles on Corrosion Activity of N80 Steel in HCl Solution 取代噻二唑对N80钢在HCl溶液中腐蚀活性的缓蚀作用
Pub Date : 2019-01-01 DOI: 10.1155/2019/1678431
M. Yadav, Sumit Kumar, D. Behera
Journal of Metallurgy has retracted the article titled “Inhibition Effect of Substituted iadiazoles on Corrosion Activity of N80 Steel in HCl Solution” [1]. e article was found to contain images reused in several other articles published by Mahendra Yadav and colleagues. e details of the reuse of images are as follows: Figure 9(b) is similar to Figure 11b in [2], Figure 17b in [3], Figure 14b in [4], and Figure 5b in [5]. Figure 9(c) is similar to Figure 11c in [2], Figure 17c in [3], and Figure 14c in [4]. In particular, Figure 9 in [1] shares the same image of a sample in HCl as Figure 11 in [2] and the same image in the presence of an inhibitor, but these represent different inhibitors in each article, AMPT, and BAL, respectively. We asked the authors to provide the underlying uncropped and unadjusted scanning electron microscopy (SEM) images, the raw data, and details of how the experiments were conducted. e corresponding author, Dr. Yadav, said the SEM work was outsourced but did not give details on where, when, or by whom this work was performed. e equipment is described as a “JEOL JSM-6380 LA analytical scanning electron microscope” in this article. However, there is no description of the scanning electron microscope in [2] and in [6] it is described as a “Scanning Electron Microscope model SEM Jeol JSM-5800.” ese are not the same model of microscope, despite these articles sharing some of the same SEM images. Dr. Yadav provided uswith replacement figures.However, they were identical for two of the articles, [1, 6], despite representing experiments with the inhibitors AMPT and ODAEODI, respectively. We were not told how these images were generated, the images were of low resolution, and the text in the images was illegible. e corresponding author agreed to retraction and we have asked the institution to formally investigate. References
《冶金学报》撤回了题为《取代二唑对N80钢在HCl溶液中腐蚀活性的抑制作用》的文章[1]。这篇文章被发现包含了Mahendra Yadav及其同事发表的其他几篇文章中重复使用的图像。图9(b)与[2]中的图11b、[3]中的图17b、[4]中的图14b、[5]中的图5b相似。图9(c)与[2]中的图11c、[3]中的图17c、[4]中的图14c相似。特别是,[1]中的图9与[2]中的图11在HCl中具有相同的图像,并且在抑制剂存在的情况下具有相同的图像,但这些分别代表了每篇文章中的不同抑制剂,AMPT和BAL。我们要求作者提供未裁剪和未调整的扫描电子显微镜(SEM)图像、原始数据和实验进行的细节。通讯作者Yadav博士说,扫描电镜的工作是外包的,但没有详细说明这项工作是在何时何地由谁完成的。e设备被描述为“JEOL JSM-6380 LA分析扫描电子显微镜”在这篇文章。然而,在[2]和[6]中没有对扫描电子显微镜的描述,它被描述为“扫描电子显微镜模型SEM Jeol JSM-5800”。尽管这些文章分享了一些相同的扫描电镜图像,但它们不是同一种显微镜模型。Yadav医生为我们提供了替换数字。然而,尽管分别用抑制剂AMPT和ODAEODI进行了实验,但两篇文章[1,6]的结果是相同的。我们没有被告知这些图像是如何生成的,图像的分辨率很低,图像中的文字难以辨认。E通讯作者同意撤稿,我们已要求机构进行正式调查。参考文献
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引用次数: 2
Physical metallurgy of modern creep-resistant steel for steam power plants: microstructure and phase transformations 蒸汽电厂用现代抗蠕变钢的物理冶金:显微组织和相变
Pub Date : 2016-11-30 DOI: 10.1155/2016/5468292
V. Igwemezie, C. C. Ugwuegbu, U. Mark
The fact that the microstructure of steel depends on its composition and the heat treatment given to it has been heavily exploited in the design of steel for power plant applications. To obtain a steel that can function at the higher temperature where power plants operate without failure for extended life, heat treatment is needed to produce fine and highly stable dispersion of carbides, nitrides, and intermetallic compounds in the microstructure of the material. A significant contribution also comes from solid solution strengthening by substitutional solutes. We review here various types of phases, microstructures, functions, and interacting effects of the various alloying elements in the design of steel for modern power plant application.
钢的显微组织取决于其成分和热处理,这一事实在电厂用钢的设计中得到了大量的利用。为了获得一种可以在更高温度下工作的钢,而发电厂在延长寿命的过程中不会出现故障,需要进行热处理,以在材料的微观结构中产生精细且高度稳定的碳化物、氮化物和金属间化合物的分散。取代溶质对固溶体的强化也起着重要的作用。本文综述了现代电厂用钢设计中各种合金元素的相、组织、功能及其相互作用。
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引用次数: 19
Microstructural and Surface Texture Analysis due to Machining in Super Austenitic Stainless Steel 超级奥氏体不锈钢加工后的显微组织和表面织构分析
Pub Date : 2016-09-25 DOI: 10.1155/2016/3685312
Mohanad Alabdullah, Ashwin Polishetty, G. Littlefair
Inferior surface quality is a significant problem faced by machinist. The purpose of this study is to present a surface texture analysis undertaken as part of machinability assessment of Super Austenitic Stainless Steel alloy-AL6XN. The surface texture analysis includes measuring the surface roughness and investigating the microstructural behaviour of the machined surfaces. Eight milling trials were conducted using combination of cutting parameters under wet machining. An optical profilometer (noncontact) was used to evaluate the surface texture at three positions. The surface texture was represented using the parameter, average surface roughness. Scanning Electron Microscope was utilised to inspect the machined surface microstructure and correlate the microstructure with the surface roughness. Results showed that maximum roughness values recorded at the three positions in the longitudinal direction (perpendicular to the machining grooves) were 1.21 μm (trial 1), 1.63 μm (trial 6), and 1.68 μm (trial 7), respectively, whereas the roughness values were greatly reduced in the lateral direction. Also, results showed that the feed rate parameter significantly influences the roughness values compared to the other cutting parameters. The microstructure of the machined surfaces was distorted by the existence of cracks, deformed edges, and bands and wear deposition due to machining process.
表面质量差是机械加工人员面临的一个重要问题。本研究的目的是提出作为超级奥氏体不锈钢合金- al6xn可加工性评估的一部分的表面织构分析。表面织构分析包括测量表面粗糙度和研究加工表面的微观组织行为。在湿法加工条件下,组合切削参数进行了8次铣削试验。使用光学轮廓仪(非接触式)在三个位置评估表面纹理。表面纹理用平均表面粗糙度参数表示。利用扫描电子显微镜对加工表面的微观组织进行了观察,并将微观组织与表面粗糙度进行了对比。结果表明,在纵向(垂直于加工槽)三个位置记录的最大粗糙度值分别为1.21 μm(试验1)、1.63 μm(试验6)和1.68 μm(试验7),而在横向上粗糙度值大大降低。结果表明,与其他切削参数相比,进给速度参数对粗糙度值有显著影响。由于加工过程产生的裂纹、边缘变形、带状变形和磨损沉积等,使加工表面的组织发生畸变。
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引用次数: 6
Bulk Mechanical Properties Testing of Metallic Marginal Glass Formers 金属边缘玻璃成型机的整体机械性能测试
Pub Date : 2016-08-18 DOI: 10.1155/2016/6508597
T. Phan, J. Kelly, M. E. Kassner, V. Eliasson, O. Graeve, A. Hodge
We developed a unique three-point bend testing apparatus to measure bulk mechanical properties of a model metallic glass alloy (SAM2X5 with nominal composition Fe49.7Cr17.1Mn1.9Mo7.4W1.6B15.2C3.8Si2.4) prepared by spark plasma sintering. The relatively large sample sizes in the present work allowed for the preparation of test specimens with a macroscale cross section (in the millimeter range) with well-controlled sample dimensions closer to standardized tests. Wire saw cutting allowed for a relatively sharp notch radius (3x smaller than previous studies) and minimal sample damage. We determined that Young’s modulus and notch fracture toughness measured by our three-point bending apparatus are 230 GPa and 4.9 MPam1/2. Also, Vickers indentation and flexure testing provided consistent results for Young’s modulus. Indentation fracture toughness measured by Vickers indentation produced values at least 50% lower than by flexure. The microscale mechanical properties testing technique presented in this work and subsequent analyses are applicable to specimens of other compositions or ones prepared by other methods.
研制了一种独特的三点弯曲试验装置,用于测量火花等离子烧结制备的SAM2X5模型金属玻璃合金(标称成分为Fe49.7Cr17.1Mn1.9Mo7.4W1.6B15.2C3.8Si2.4)的整体力学性能。本工作中相对较大的样本量允许制备具有宏观横截面(毫米范围内)的试样,其样品尺寸控制良好,更接近标准化测试。线锯切割允许相对锋利的切口半径(比以前的研究小3倍)和最小的样品损坏。我们确定了三点弯曲仪测量的杨氏模量和缺口断裂韧性分别为230 GPa和4.9 mpam /2。此外,维氏压痕和弯曲测试提供了一致的杨氏模量结果。用维氏压痕法测定的压痕断裂韧性比用挠曲法测定的压痕断裂韧性至少低50%。本文提出的微尺度力学性能测试技术及其后续分析也适用于其他成分或用其他方法制备的试样。
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引用次数: 5
Review on Vertical Twin-Roll Strip Casting: A Key Technology for Quality Strips 立式双辊带钢连铸技术——高质量带钢的关键技术综述
Pub Date : 2016-08-09 DOI: 10.1155/2016/1038950
Seshadev Sahoo
Nowadays near-net-shape casting technology is an important area of research in the iron and steel industry. Among different kinds of near-net-shape casting process, twin-roll casting process has received much attention among researchers. Twin-roll casting (TRC) has been the subject of extensive research, not only to develop the technology but also to achieve an understanding of microstructural evolution and to produce quality strips. The main issues concerning the design and operation of twin-roll casters are metal-mold heat transfer, metal delivery system, and their possible effects on the solid shell formation and characteristics of the strips. The present review gives an idea about the process aspect, modeling, and quality issues in vertical twin-roll strip casting process and helps to improve the design of twin-roll strip caster.
近净形铸造技术是目前钢铁工业研究的一个重要领域。在各种近净形铸造工艺中,双辊铸造工艺受到了研究人员的广泛关注。双辊连铸(TRC)一直是广泛研究的主题,不仅是为了发展技术,也是为了了解微观组织的演变和生产高质量的带钢。关于双辊连铸机的设计和运行的主要问题是金属-模具传热,金属输送系统,以及它们对带钢固体壳形成和特性的可能影响。本文综述了双辊带钢立式连铸机的工艺、造型和质量问题,有助于改进双辊带钢连铸机的设计。
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引用次数: 14
Structural Analysis and Magnetic Properties of FeCo Alloys Obtained by Mechanical Alloying 机械合金化制备FeCo合金的结构分析和磁性能
Pub Date : 2016-07-13 DOI: 10.1155/2016/8347063
F. S. Jesús, A. Bolarín-Miró, C. Escobedo, G. Torres-Villaseñor, P. Vera-Serna
A systematic study on the structural and magnetic properties of alloys (, in wt. percent) obtained by mechanical alloying is presented. Elemental powders of Fe and Co mixed in an adequate weight ratio were milled at room temperature in a shaker mixer mill using vials and balls of hardened steel as milling media with a ball : powder weight ratio of 12 : 1. The mixtures were milled for 3 h. The results show that, after milling, for almost all the composition (up to ), solid solutions based on bcc structures were obtained. For Co-rich alloys (), different phases were found, revealing the formation of a metastable intermetallic phase (FeCo, wairauite) together with fcc-Co and hcp-Co phases. The specific saturation magnetization increases by increasing Co content, reaching a maximum value of 225 emu/g for hcp-Fe70Co30, and then it shows a diminution up to 154 emu/g for bcc-Fe30Co70. All studied alloys () present low coercivity, in the range from 0 to 65 Oe, which is lower than reported. The coercivity increases with the increment in Co, reaching a maximum of 64.1 Oe for Fe40Co60. After that, the coercivity falls up to 24.5 Oe for Co-rich alloys, which make them a very low coercive material.
本文对机械合金化所得合金的组织和磁性作了系统的研究。铁和钴元素粉末按适当的重量比混合,在室温下在摇床混合机中使用小瓶和淬火钢球作为研磨介质,球与粉的重量比为12:1。将混合物研磨3小时。结果表明,研磨后,几乎所有成分(高达)都得到了基于bcc结构的固溶体。对于富co合金(),发现了不同的相,揭示了亚稳金属间相(FeCo, waairauite)与fcc-Co和hcp-Co相的形成。比饱和磁化强度随Co含量的增加而增大,hcp-Fe70Co30的饱和磁化强度最大值为225 emu/g, bcc-Fe30Co70的饱和磁化强度减小至154 emu/g。所有研究的合金都表现出较低的矫顽力,在0 ~ 65欧安的范围内,这比报道的要低。矫顽力随Co含量的增加而增大,Fe40Co60矫顽力最大值为64.1 Oe。在此之后,富钴合金的矫顽力降至24.5 Oe,这使其成为一种非常低的矫顽力材料。
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引用次数: 36
Anticorrosion Activity of 8-Quinoline Sulphonyl Chloride on Mild Steel in 1 M HCl Solution 8-喹啉磺酰氯在1m HCl溶液中对低碳钢的防腐活性
Pub Date : 2016-02-29 DOI: 10.1155/2016/8095206
R. Sundaram, M. Sundaravadivelu
An anticorrosion activity of 8-quinoline sulphonyl chloride (8-QSC) on mild steel in 1 M HCl solution was studied by weight loss (WL) method and electrochemical methods, namely, electrochemical impedance spectroscopy (EIS), Tafel polarization (TP), and linear polarization resistance (LPR). Results obtained from WL method, EIS, TP, and LPR, showed that 8-QSC is a good corrosion inhibitor for mild steel in 1 M HCl solution. The results indicated that the inhibition efficiency and extent of surface coverage were increased with increase in inhibitor concentration and decrease in the corrosion rate. This is due to the formation of protective film on the surface of mild steel. Adsorption of 8-QSC on the mild steel surface was found to obey the Langmuir adsorption isotherm. A Tafel plot indicates that the used inhibitor behaves predominantly as cathodic type. The surface morphology of the mild steel was studied by Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray (EDX) Spectroscopy techniques. All the methods give the same order of inhibition efficiencies.
采用失重法(WL)和电化学方法,即电化学阻抗谱法(EIS)、塔菲尔极化法(TP)和线性极化电阻法(LPR)研究了8-喹啉磺酰氯(8-QSC)在1 M盐酸溶液中对低碳钢的防腐性能。WL法、EIS法、TP法和LPR法的结果表明,8-QSC在1 M HCl溶液中是一种较好的低碳钢缓蚀剂。结果表明,随着缓蚀剂浓度的增加和腐蚀速率的降低,缓蚀剂的缓蚀效率和表面覆盖范围增大。这是由于在低碳钢表面形成保护膜。8-QSC在低碳钢表面的吸附服从Langmuir吸附等温线。塔菲尔图表明,所使用的缓蚀剂主要表现为阴极型。利用扫描电镜(SEM)和能量色散x射线(EDX)光谱技术研究了低碳钢的表面形貌。所有方法的抑制效率都是相同的。
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引用次数: 18
Metallurgical and Machinability Characteristics of Wrought and Selective Laser Melted Ti-6Al-4V 变形和选择性激光熔化Ti-6Al-4V的冶金和切削性能
Pub Date : 2016-01-01 DOI: 10.1155/2016/7407918
Manikandakumar Shunmugavel, Ashwin Polishetty, J. Nomani, M. Goldberg, G. Littlefair
This research work presents a machinability study between wrought grade titanium and selective laser melted (SLM) titanium Ti-6Al-4V in a face turning operation, machined at cutting speeds between 60 and 180 m/min. Machinability characteristics such as tool wear, cutting forces, and machined surface quality were investigated. Coating delamination, adhesion, abrasion, attrition, and chipping wear mechanisms were dominant during machining of SLM Ti-6Al-4V. Maximum flank wear was found higher in machining SLM Ti-6Al-4V compared to wrought Ti-6Al-4V at all speeds. It was also found that high machining speeds lead to catastrophic failure of the cutting tool during machining of SLM Ti-6Al-4V. Cutting force was higher in machining SLM Ti-6Al-4V as compared to wrought Ti-6Al-4V for all cutting speeds due to its higher strength and hardness. Surface finish improved with the cutting speed despite the high tool wear observed at high machining speeds. Overall, machinability of SLM Ti-6Al-4V was found poor as compared to the wrought alloy.
本研究研究了锻造级钛和选择性激光熔化(SLM)钛Ti-6Al-4V在表面车削操作中的可加工性,切削速度在60到180 m/min之间。研究了刀具磨损、切削力和加工表面质量等可加工性特性。在SLM Ti-6Al-4V的加工过程中,涂层剥离、粘附、磨损、摩擦和切屑磨损机制是主要的。在所有速度下,与变形Ti-6Al-4V相比,SLM Ti-6Al-4V的最大侧面磨损更高。研究还发现,高速切削会导致Ti-6Al-4V型SLM刀具的灾难性失效。由于Ti-6Al-4V的强度和硬度更高,在所有切削速度下,加工SLM Ti-6Al-4V时的切削力都高于锻造Ti-6Al-4V。表面光洁度随着切削速度的提高而提高,尽管在高加工速度下观察到高刀具磨损。总体而言,与变形合金相比,SLM Ti-6Al-4V的可加工性较差。
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引用次数: 24
Through-Thickness Compression Testing of Commercially Pure (Grade II) Titanium Thin Sheet to Large Strains 商业纯(II级)钛薄板对大应变的全厚压缩试验
Pub Date : 2016-01-01 DOI: 10.1155/2016/6178790
K. K. Smith, M. E. Kassner
This study examined the through-thickness ( -direction) compressive stress versus strain behavior of 99.76% commercially pure (grade II) titanium sheet with relatively small grain size. The current study complemented earlier compression studies by examining a very thin (1.60 mm) sheet and deforming the Ti by successive compression tests to relatively large strains. The low aspect ratio, of the compression specimens extracted from the sheet, led to frictional effects that can create high triaxial stresses complicating the uniaxial stress versus strain behavior analysis. Nonetheless, reasonable estimates were made of the through-thickness large-strain behavior of a commercially pure (grade II) thin Ti sheet to relatively large true strains of about 1.0.
本研究检测了99.76%商业纯钛(II级)相对较小晶粒尺寸的全厚度(方向)压应力与应变行为。目前的研究补充了早期的压缩研究,通过检查非常薄(1.60 mm)的薄片,并通过连续的压缩测试使Ti变形到相对较大的应变。从薄片中提取的压缩试样的低纵横比导致摩擦效应,从而产生高三轴应力,使单轴应力与应变行为分析复杂化。尽管如此,对商业纯钛(II级)薄板的全厚大应变行为进行了合理的估计,其真实应变相对较大,约为1.0。
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引用次数: 3
Adoption of Sinter Addition in Steelmaking Converter to Control Spitting 炼钢转炉采用添加烧结料控制吐渣
Pub Date : 2015-12-15 DOI: 10.1155/2015/187042
S. Gupta, A. Prasad, A. Chatterjee, Manoranjan Kumar, Somnath Ghosh, R. Datta
Steel Melting Shop-I, Rourkela Steel Plant, Rourkela, produces 0.5 MT of various special steels through BOF-VAR/VOR-LF-CC route. One of the most serious problems in BOF operations was lance skulling, hood jamming, and build-up of metal in the mouth and cone of the furnace due to spitting and slopping. As spitting occurring during blowing increases, these particles of metal are deposited inside the mouth and cone and affect badly BOF productivity. In the present work, control of spitting has been established by addition of sinter during the period of spitting. It also helped to improve the slag formation and fluidity of slag through increase of FeO content during peak decarburisation period.
Rourkela钢铁厂炼钢车间i,通过BOF-VAR/VOR-LF-CC路线生产0.5公吨各种特种钢。在转炉操作中,最严重的问题之一是枪头脱落、引擎盖堵塞以及由于吐槽和倾倒而在炉口和炉锥中积聚金属。随着吹气过程中吐痰的增加,这些金属颗粒沉积在口和锥内,严重影响转炉生产率。在本工作中,通过在喷砂过程中添加烧结矿来控制喷砂。在脱碳高峰期,通过提高FeO含量,有助于改善渣的形成和渣的流动性。
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引用次数: 1
期刊
Journal of Metallurgy
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