Libia-Sofia Sandoval-Rodríguez, W. Cañas-Marín, Ramiro Martínez-Rey
{"title":"RHEOLOGICAL BEHAVIOR OF WATER-IN-OIL EMULSIONS OF HEAVY AND EXTRA-HEAVY LIVE OILS: EXPERIMENTAL EVALUATION","authors":"Libia-Sofia Sandoval-Rodríguez, W. Cañas-Marín, Ramiro Martínez-Rey","doi":"10.29047/01225383.37","DOIUrl":null,"url":null,"abstract":"Stable emulsions were prepared with heavy and extra-heavy live oils by using a set-up recently built at Ecopetrol S.A. - Instituto Colombiano del Petroleo (ICP). This equipment permits to prepare water-in-oil emulsions at reservoir conditions without any change on the overall hydrocarbon composition. The live emulsions were prepared with water contents up to 26% in volume. Then, a capillary viscometer was used to study the rheological behavior of these emulsions at different shear rates and pressures up to 24.2 MPa. The experimental results permit to conclude that the prepared and evaluated emulsions have a Newtonian behavior for the conditions of water contents, shear rates, pressures and temperature (60°C) here studied. For these emulsions, a logarithmic behavior of the viscosity with respect to pressure and water content was also observed.","PeriodicalId":10235,"journal":{"name":"Ciencia Tecnologia y Futuro","volume":"71 1","pages":"5-22"},"PeriodicalIF":0.0000,"publicationDate":"2014-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ciencia Tecnologia y Futuro","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.29047/01225383.37","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5
Abstract
Stable emulsions were prepared with heavy and extra-heavy live oils by using a set-up recently built at Ecopetrol S.A. - Instituto Colombiano del Petroleo (ICP). This equipment permits to prepare water-in-oil emulsions at reservoir conditions without any change on the overall hydrocarbon composition. The live emulsions were prepared with water contents up to 26% in volume. Then, a capillary viscometer was used to study the rheological behavior of these emulsions at different shear rates and pressures up to 24.2 MPa. The experimental results permit to conclude that the prepared and evaluated emulsions have a Newtonian behavior for the conditions of water contents, shear rates, pressures and temperature (60°C) here studied. For these emulsions, a logarithmic behavior of the viscosity with respect to pressure and water content was also observed.
稳定乳状液是用哥伦比亚国家石油公司(Ecopetrol S.A. - Instituto Colombiano del Petroleo, ICP)最近建立的装置用重质和超重质活油制备的。该设备允许在储层条件下制备油包水乳液,而不会改变整体碳氢化合物组成。制备的乳状液含水量可达26%。然后,用毛细管粘度计研究了不同剪切速率和最高24.2 MPa压力下乳剂的流变行为。实验结果表明,在所研究的含水量、剪切速率、压力和温度(60°C)条件下,所制备和评价的乳剂具有牛顿力学行为。对于这些乳剂,粘度对压力和含水量的对数行为也被观察到。