Recovery of Metals from Dry Shot Blast Waste Generated in the Stainless-Steel Production Process

S. Khumkoa, T. akhiaw, N. Ma-ud, P. Khamseetha, P. Hathong, P. Laokhen, C. Kansomket
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Abstract

Dry shot blast generated during stainless steel production contains high content of valued metals such as iron chromium and nickel. These metals are in the form of oxides and it can be used as a raw material in iron and steel. This work aims to study the feasibility of metals recovery from dry shot blast by smelting reduction process. Smelting reduction of dry shot blast by using coking coal as reductant was conducted in an induction furnace. The effect of metallurgical parameters e.g. stoichiometry ratio of reductant per oxygen containing in dry shot blast, CaO/SiO2 of slag forming and CaF2 in slag, on %recovery of metal product was investigated. The results based on this study showed that the weight of metal product increases with increased the amount of coke to about 1.5 of stoichiometric molar ratio. Increasing of coke above this amount leads to decrease %recovery of metal product. Moreover, the weight of metal product is increased when the ratio of CaO/SiO2 in slag decreased from 2 to 1. The chemical composition of the metal product is in the range of commercial grade and it can be used as raw materials to produce steel and cast iron alloy.Dry shot blast generated during stainless steel production contains high content of valued metals such as iron chromium and nickel. These metals are in the form of oxides and it can be used as a raw material in iron and steel. This work aims to study the feasibility of metals recovery from dry shot blast by smelting reduction process. Smelting reduction of dry shot blast by using coking coal as reductant was conducted in an induction furnace. The effect of metallurgical parameters e.g. stoichiometry ratio of reductant per oxygen containing in dry shot blast, CaO/SiO2 of slag forming and CaF2 in slag, on %recovery of metal product was investigated. The results based on this study showed that the weight of metal product increases with increased the amount of coke to about 1.5 of stoichiometric molar ratio. Increasing of coke above this amount leads to decrease %recovery of metal product. Moreover, the weight of metal product is increased when the ratio of CaO/SiO2 in slag decreased from 2 to 1. The chemical composition of the metal product is in the range of commercial grade and it can be used as raw materials to produce steel and cast iron alloy.
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从不锈钢生产过程中产生的干抛丸废渣中回收金属
不锈钢生产过程中产生的干抛丸含有高含量的贵重金属,如铁、铬和镍。这些金属以氧化物的形式存在,可用作钢铁的原料。本文旨在研究采用熔炼还原法回收干抛丸中金属的可行性。以焦煤为还原剂,在感应炉中对干抛丸进行了冶炼还原。考察了干抛丸中还原剂含氧化学计量比、成渣中CaO/SiO2和渣中CaF2等冶金参数对金属产品回收率的影响。研究结果表明,随着焦炭用量的增加,金属产品的重量增加,焦炭的化学计量摩尔比约为1.5。焦炭添加量超过此量会导致金属产品回收率下降。当渣中CaO/SiO2的比值由2降到1时,金属产品的重量增加。金属制品的化学成分在工业级范围内,可用作生产钢铁和铸铁合金的原料。不锈钢生产过程中产生的干抛丸含有高含量的贵重金属,如铁、铬和镍。这些金属以氧化物的形式存在,可用作钢铁的原料。本文旨在研究采用熔炼还原法回收干抛丸中金属的可行性。以焦煤为还原剂,在感应炉中对干抛丸进行了冶炼还原。考察了干抛丸中还原剂含氧化学计量比、成渣中CaO/SiO2和渣中CaF2等冶金参数对金属产品回收率的影响。研究结果表明,随着焦炭用量的增加,金属产品的重量增加,焦炭的化学计量摩尔比约为1.5。焦炭添加量超过此量会导致金属产品回收率下降。当渣中CaO/SiO2的比值由2降到1时,金属产品的重量增加。金属制品的化学成分在工业级范围内,可用作生产钢铁和铸铁合金的原料。
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