{"title":"Kinetics of thermal decomposition of acetic anhydride in flow and static systems","authors":"P. G. Blake, A. Speis","doi":"10.1039/J29710001877","DOIUrl":null,"url":null,"abstract":"The thermal decomposition of gaseous acetic anhydride has been studied in flow and static apparata between 197 and 370°C. The decomposition, which yields keten and acetic acid only, is homogeneous and unimolecular, k= 1011·27 exp (–134,700/RT) s–1.","PeriodicalId":17268,"journal":{"name":"Journal of The Chemical Society B: Physical Organic","volume":"69 1","pages":"1877-1878"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society B: Physical Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J29710001877","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
The thermal decomposition of gaseous acetic anhydride has been studied in flow and static apparata between 197 and 370°C. The decomposition, which yields keten and acetic acid only, is homogeneous and unimolecular, k= 1011·27 exp (–134,700/RT) s–1.
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