Pengaruh Penambahan Variasi KJ-CTAB Terhadap Karakteristik ZnO/KJ-CTAB yang Disintesis Menggunakan Metode Impregnasi Basah

Azzalina Nur Alviana, Aulia Dewi Rosanti, Rizky Arief Shobirin, Fahmi Hidayat
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Abstract

Semiconductor photocatalysts have great potential in solving environmental problems. The photocatalyst process using a semiconductor is one of the technology to oxidize organic compounds such as dyes. Orange peel (KJ) is one of the adsorbents that have the potential for purification of dyes that increase the photocatalytic activity of ZnO material. This study aims to determine the optimum variation of KJ-CTAB to be added to ZnO material. The results of the synthesis of ZnO/KJ-CTAB varasis 1:25, 2:25, and 3:25 (w/v) using the wet impregnation method were characterized on IR, XRD, SEM, DR-UV, and BET instruments. The results showed that FTIR also showed the presence of ZnO bonds in all samples, C-H in samples varied from 1:25, 2:25, and 3:25 (w/v). The XRD results showed that the percentage of crystallinity decreased and the SEM results showed that ZnO/KJ-CTAB 1:25 had a more homogeneous morphology. Based on the results of DR-UV ZnO/KJ-CTAB 1: 25 (w/v) has a band gap energy value of 3.20 eV which is good for use in photocatalyst processes. BET results show that all samples belong to the mesoporous size.
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使用湿内植入方法合成的KJ-CTAB变体对ZnO/KJ-CTAB特性的影响
半导体光催化剂在解决环境问题方面具有很大的潜力。利用半导体的光触媒工艺是氧化染料等有机化合物的技术之一。桔皮(KJ)是一种具有纯化染料潜力的吸附剂,可以提高ZnO材料的光催化活性。本研究旨在确定ZnO材料中KJ-CTAB的最佳添加量。采用湿浸渍法制备1:25、2:25和3:25 (w/v)的ZnO/KJ-CTAB变异体,用IR、XRD、SEM、DR-UV和BET等仪器对其进行了表征。结果表明,FTIR也显示出所有样品中都存在ZnO键,样品的C-H变化范围为1:25,2:25和3:25 (w/v)。XRD结果表明,ZnO/KJ-CTAB 1:25的结晶度降低,SEM结果表明ZnO/KJ-CTAB 1:25的形貌更加均匀。根据DR-UV实验结果,ZnO/KJ-CTAB 1:25 (w/v)的能带能值为3.20 eV,适合于光催化工艺。BET结果表明,所有样品均属于介孔尺寸。
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