Enhancement of the Texture & Morphology of Nano γ-Alumina as a Support for Naphtha Reforming Catalyst

Mustafa H. Flayyih, Mohammed S. Theib
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Abstract

The morphology of nano gamma alumina affects the molecule adsorption-desorption phenomena. In this case, manipulating the surface area, pore volume, and pore size by the technique of preparation to control the morphology and textural properties of gamma alumina. Washing of the synthesized boehmite gel with methanol has a significant effect. The co-precipitation method was used to prepare nano gamma alumina, which is involved by adding drop-by-drop ammonium hydroxide and aluminum nitrate nonahydrate solutions to a cetyltrimethylammonium bromide (CTAB) cationic surfactant solution at 30 C and adjust PH to 8. Nitrogen adsorption-desorption analysis (ASAP 2020), Atomic Force Microscope (AFM), and X-Ray Diffraction (XRD) were used to examine the obtained material.   Surface area (362 m2/g), pore volume (0.51 cm3/g), pore size (5.2 nm), and narrow pore size distribution were obtained.
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作为石脑油重整催化剂载体的纳米γ-氧化铝结构和形貌的增强
纳米氧化铝的形貌影响着分子的吸附-脱附现象。在这种情况下,通过制备技术操纵表面积、孔隙体积和孔隙大小来控制γ氧化铝的形态和结构特性。合成的薄水铝石凝胶用甲醇洗涤效果显著。采用共沉淀法,将氢氧化铵和硝酸铝溶液滴入十六烷基三甲基溴化铵(CTAB)阳离子表面活性剂溶液中,温度为30℃,PH调节为8,制备纳米氧化铝。采用氮吸附-解吸分析(ASAP 2020)、原子力显微镜(AFM)和x射线衍射(XRD)对所得材料进行了表征。得到了比表面积(362 m2/g)、孔体积(0.51 cm3/g)、孔径(5.2 nm)和较窄的孔径分布。
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