Treatment of Activated Carbon with Potassium Permanganate for Improving the Efficiency of Ethylene Removal Released from Climacteric Fruits

Inaam Al- Saty, Antoine Youssef
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Abstract

The phytohormone ethylene is one of the main causes of postharvest spoilage of fruits and vegetables. The effective management of ethylene concentration is of great importance to reduce postharvest losses of fruits and vegetables. The reduction in ethylene caused by using KMnO4 was found to delay the ripening of many climacteric fruits such as apple, bananas, melons and tomatoes. Interestingly, the general aim of this work is to evaluate the effectiveness of KMnO4 in reducing ethylene concentration during storage of climacteric fruit. For this purpose, ethylene-enriched mixture was passed inside a cylinder with a bed of activated carbon treated with KMnO4 and t gas samples entering and exiting the cylinder were analyzed for ethylene concentration by injecting in gas chromatography (GC-FID) after 15, 30, and 45 minutes and results obtained were compared with a similar set up but with only activated carbon as ethylene adsorber. The results showed that maximal ethylene removal was in the cylinder with activated carbon treated with KMnO4 which removed 91.71% of ethylene 45 min after treatment compared with 61.93% ethylene removal by only using the activated carbon. The results also revealed that the activated carbon with KMnO4 10 days after storage reduced ethylene concentration by 43.94% compared with 28.77% for the activated carbon. Keywords: Ethylene, activated carbon, KMnO4, climacteric fruit, adsorption, GC-FID.
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高锰酸钾处理活性炭提高更年期果实乙烯脱除效率
植物激素乙烯是水果和蔬菜采后变质的主要原因之一。乙烯浓度的有效管理对减少果蔬采后损失具有重要意义。使用KMnO4引起的乙烯减少被发现延迟了许多更年期水果的成熟,如苹果、香蕉、瓜和西红柿。有趣的是,这项工作的总体目的是评估KMnO4在更年期水果储存期间降低乙烯浓度的有效性。为此,将富含乙烯的混合物放入经KMnO4处理过的活性炭床中,并在15、30和45分钟后通过气相色谱法(GC-FID)对进出气缸的气体样品进行乙烯浓度分析,并将所得结果与仅使用活性炭作为乙烯吸附剂的类似装置进行比较。结果表明,活性炭经KMnO4处理后45 min乙烯去除率最高,达到91.71%,而单纯使用活性炭的乙烯去除率为61.93%。结果还表明,贮存10 d后,KMnO4对乙烯浓度的降低率为43.94%,而活性炭对乙烯浓度的降低率为28.77%。关键词:乙烯,活性炭,KMnO4,更年期果实,吸附,GC-FID
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