Study on volume swell and mechanical properties of fuel system elastomers with Fischer–Tropsch fuel for diesel engines

Tao Wu, Wu-gao Zhang, Haiyong Peng, Haibo Zhang
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Abstract

The compatibility of elastomers used in engine fuel system with Fischer–Tropsch (FT) fuel is essential, but there is very limited research available on it. In this work, the compatibility between four types of commonly used elastomers in fuel system and FT fuel was experimentally investigated. The assessed elastomers including nitrile butadiene rubber (NBR), ethylene propylene diene-monomer rubber (EPDM), fluoroelastomer (FKM), and chlorinated polyethylene (CPE) were exposed to FT fuel which derived from natural gas for 21 days. The properties of the elastomers such as mass, volume, hardness, tensile strength, elongation at break, and tear strength were measured before and after immersion, at the same time the change rates of these properties were calculated. The results demonstrated that all properties of EPDM deteriorated significantly after soak, and its compatibility with FT fuel was the worst, making it unsuitable for FT engines. NBR, FKM, and CPE all showed low rates of property change, with FKM exhibiting the greatest compatibility performance with FT fuel. Additionally, the O-rings made of FKM were submerged in FT fuel and diesel for 7 days, 14 days, and 21 days, respectively. It was found that the mass and volume variations of FKM O-rings in FT fuel were negligible and comparable with those of diesel fuel.
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柴油机用费托燃料燃料系统弹性体的体积膨胀和力学性能研究
发动机燃油系统用弹性体与费托燃料的相容性是至关重要的,但在这方面的研究非常有限。实验研究了燃料系统中常用的四种弹性体与FT燃料的相容性。被评估的弹性体包括丁腈橡胶(NBR)、乙丙二烯单体橡胶(EPDM)、氟弹性体(FKM)和氯化聚乙烯(CPE),这些弹性体暴露在天然气衍生的FT燃料中21天。测定了浸渍前后弹性体的质量、体积、硬度、抗拉强度、断裂伸长率、撕裂强度等性能,并计算了这些性能的变化率。结果表明,EPDM浸泡后各项性能均显著恶化,与FT燃料的相容性最差,不适用于FT发动机。NBR、FKM和CPE均表现出较低的性能变化速率,其中FKM与FT燃料表现出最大的相容性。此外,将FKM制成的o型圈分别浸泡在FT燃料和柴油中7天、14天和21天。结果表明,FKM o型环在FT燃料中的质量和体积变化可以忽略不计,与柴油燃料相当。
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