Kinetic Modeling of Dynamic Aspects of the Standard NH3-SCR Reaction Over V2O5-WO3/TiO2 and Fe-Zeolite Commercial Catalysts for the Aftertreatment of Diesel Engines Exhausts
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引用次数: 20
Abstract
Dynamic kinetic data collected over commercial V2 O5 -WO3 /TiO2 and Fe-zeolite catalysts analyzing the standard NH3 -SCR of NO for the abatement of NOx from vehicle exhausts showed transient effects at low temperatures related to the inhibiting action of excess ammonia. In order to describe such transient effects, a specific rate expression accounting for NH3 inhibition of the standard SCR reaction is needed in mathematical models of real SCR converters. We present herein a dual-site Mars-Ven Krevelen-type rate equation suitable to describe dynamic features associated with ammonia injection and shut-off over both V-based and Fe-zeolite catalysts.
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