Bianka Huszár , Réka Henyecz , Zoltán Mucsi , György Keglevich
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引用次数: 1
Abstract
Our group introduced a green protocol for the Pd(OAc)2- or NiCl2-catalyzed P–C coupling reaction of aryl halides and various > P(O)H-compounds under MW conditions without directly added P-ligands. The reactivity of a few aryl derivatives in the Pd(OAc)2-catalyzed Hirao reaction was also studied. An induction period was observed in the reaction of bromobenzene and diphenylphosphine oxide. Finally, the less known copper(I)-promoted P–C coupling reactions were investigated experimentally. The mechanism was explored by quantum chemical calculations.
本课题组提出了一种在MW条件下不直接添加P配体的Pd(OAc)2-或nicl2催化芳基卤化物与各种> P(O) h -化合物的P- c偶联反应的绿色方案。研究了几种芳基衍生物在Pd(OAc)2催化的Hirao反应中的反应活性。在溴苯和二苯基氧化膦的反应中观察到一个诱导期。最后，对铜(I)促进的P-C偶联反应进行了实验研究。通过量子化学计算探索了这一机制。图形抽象
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Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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