Fabrication and characterization of a PVDF/PLA membrane made by electrospinning as a flexible temperature sensor

G. Rodríguez-Roldán, E. Suaste-Gómez, Héctor Reyes-Cruz
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Abstract

In this work, a temperature characterization of a PVDF/PLA membrane made by electrospinning technique is presented. Electrospinning is a versatile method to generate fibers made of a variety of materials such as ceramics or polymers that can reach the nanometric range. Polyvinylidene difluoride (PVDF) is a piezoelectric smart polymer which is often combined with other materials in order to improve or modify its properties. This work was focused in the fabrication and characterization of electrospun PVDF/PLA (50/50 wt%) membranes as a polymeric temperature sensor. Dielectric behavior of the membrane by applying an external stimuli such as temperature was observed. Results of this behavior showed a linear response relating temperature and the dielectric constant of the membrane. The membrane was examinated using scanning electron microscope (SEM) techniques. As a result, low porous flexible membranes were obtained with fiber diameters in a range from 50 nm to 200 nm. In conclusion, polymeric piezoelectric membranes are a promising tool in fields such as biomedical engineering, robotics and electronics as scaffolds, sensors or actuators due to their ferroelectric nature.
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静电纺丝制PVDF/PLA柔性温度传感器膜的制备与表征
本文研究了静电纺丝法制备PVDF/PLA膜的温度特性。静电纺丝是一种多用途的方法,可以产生由各种材料制成的纤维,如陶瓷或聚合物,可以达到纳米范围。聚偏二氟乙烯(PVDF)是一种压电型智能聚合物,常与其他材料结合以改善或修饰其性能。这项工作的重点是制备和表征静电纺PVDF/PLA (50/50 wt%)膜作为聚合物温度传感器。通过施加外部刺激,如温度,观察了膜的介电行为。结果表明,薄膜的介电常数与温度呈线性关系。用扫描电镜(SEM)技术对膜进行了检测。结果,获得了纤维直径在50 ~ 200 nm范围内的低孔柔性膜。总之,聚合物压电膜由于其铁电性质,在生物医学工程、机器人和电子等领域作为支架、传感器或执行器是一种很有前途的工具。
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