Synthesis, Structural and Electrical Studies of Li-Ni-Cu Nano Ferrites

IF 0.4 Q4 CHEMISTRY, MULTIDISCIPLINARY Acta Chemica Iasi Pub Date : 2018-07-01 DOI:10.2478/achi-2018-0001
Shashidhar N. Adarakatti, Veeresh S. Pattar, Prashant K. Korishettar, B. V. Grampurohit, R. G. Kharabe, A. Kulkarni, S. Mathad, C. S. Hiremath, R. B. Pujar
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引用次数: 3

Abstract

Abstract Li-Ni ferrite has gained great scientific elicit owing to of its unparalleled properties and applications. The copper doped Li-Ni ferrite has been synthesized by sucrose method. The structure was characterized by X-ray diffraction, which has confirmed the formation of single-phase spinel structure. X-ray diffraction and FTIR data reveals the formation of cubic structure phase. Unit cell parameters vary with copper content; overall variation of the unit cell parameters obeys Vegard’s law. The main absorption bands of spinel ferrite have appeared through IR absorption spectra recorded in the range of 300–700 cm−1. The copper concentration dependence of lattice parameters obeys Vegard’s law. DC electrical resistivity of the prepared samples decreases with increasing in the temperature which shows the semiconducting behaviour of all nano ferrites. The most prominent influence copper doping on the electrical properties of Li-Ni ferrites has been reported.
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Li-Ni-Cu纳米铁氧体的合成、结构和电学研究
摘要Li-Ni铁氧体以其无可比拟的性能和应用受到了广泛的科学关注。采用蔗糖法制备了掺杂铜的锂镍铁氧体。通过x射线衍射对其结构进行了表征,证实其为单相尖晶石结构。x射线衍射和FTIR数据显示立方结构相的形成。单体电池参数随铜含量的变化而变化;细胞参数的总体变化服从维加德定律。尖晶石铁素体的主要吸收带出现在300-700 cm−1的红外吸收光谱中。晶格参数对铜浓度的依赖性符合维加德定律。制备的样品的直流电阻率随温度的升高而降低,显示出所有纳米铁氧体的半导体特性。铜掺杂对Li-Ni铁氧体电学性能的影响最为显著。
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Acta Chemica Iasi
Acta Chemica Iasi CHEMISTRY, MULTIDISCIPLINARY-
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