{"title":"Syntheses of Novel Net-worked Hybrid Copolymers with Alternative Tantalum-Organic Moieties.","authors":"Ryoichi Kudo, H. Matsui, M. Yoshihara","doi":"10.1246/NIKKASHI.2002.371","DOIUrl":null,"url":null,"abstract":"タンタルブトキシドと種々の有機ジオールとの反応を行ったところ,タンタル-有機基交互構造を有する新規ハイブリッド共重合体が生成した.また,生成物の形状は,導入する有機基の種類によって形状が変化することが判明した.さらに,生成物の電子物性を検討するためにESRスペクトルおよびab-initio分子軌道計算を行ったところ,共役系有機基を導入した系において,交互構造内で有機骨格よりタンタル原子上へ電子移動が生じていることが判明した.","PeriodicalId":19311,"journal":{"name":"Nippon Kagaku Kaishi","volume":"22 1","pages":"371-375"},"PeriodicalIF":0.0000,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nippon Kagaku Kaishi","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1246/NIKKASHI.2002.371","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}