Modelling the High-Temperature Strengthening of Ni-Based Superalloys With Cuboidal γ’-Phase Particles

Liberty Wu, T. Osada, T. Yokokawa, Yatao Chang, K. Kawagishi
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Abstract

The development of advanced Ni-based superalloys for gas turbine applications is strongly reliant on alloy strength design and optimisation through microstructure control. Herein, a new model of precipitation strengthening in Ni-based superalloys with large amounts of cuboidal γ’ particles is proposed and directly validated using commercial alloy (Alloy720Li)-based single-crystal tie-line model alloys with specially designed γ’ particle sizes and volume fractions. All factors responsible for Ni-based superalloy strengthening, including the γ/γ’ mixture, particle strengthening, and solid solution strengthening are extracted from the compressive stress-strain curves performed over a wide temperature range. The strength increment due to particle strengthening is predicted for five model alloys with various γ’-particle volume fractions, sizes, and shapes. The pair-coupling model assuming the presence of cuboidal γ’ particles accurately predicts alloy strength over a wide temperature range (up to 760 °C) for volume fractions of >45%, whereas the classical model assuming spherical γ’ particles is valid only for volume fractions of <20%. Thus, the former model is much more accurate than classical models across wider volume fractions up to the disc service temperature, contributing to the design of further strengthened superalloys.
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用立方γ′相颗粒模拟ni基高温合金的高温强化
用于燃气轮机的先进镍基高温合金的开发非常依赖于合金强度设计和通过微观结构控制进行优化。本文提出了一种含有大量立方γ′颗粒的ni基高温合金的析出强化新模型,并使用具有特殊设计的γ′粒径和体积分数的商业合金(Alloy720Li)基单晶系线模型合金直接验证了该模型。ni基高温合金强化的所有因素,包括γ/γ′混合物、颗粒强化和固溶体强化,都是从宽温度范围内的压应力-应变曲线中提取出来的。对具有不同γ′-颗粒体积分数、尺寸和形状的5种模型合金进行了预测。假设立方体γ′颗粒存在的对耦合模型可以准确预测体积分数>45%的合金在宽温度范围(高达760°C)内的强度,而假设球形γ′颗粒存在的经典模型仅适用于体积分数<20%的合金。因此,在更宽的体积分数范围内,前一种模型比传统模型更精确,直至阀瓣使用温度,这有助于进一步强化高温合金的设计。
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