Optically controlled polariton condensate molecules

E. Cherotchenko, H. Sigurdsson, Alexis Askitopoulos, A. Nalitov
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引用次数: 8

Abstract

A condensed matter platform for analogue simulation of complex two-dimensional molecular bonding configurations, based on optically trapped exciton-polariton condensates is proposed. The stable occupation of polariton condensates in the excited states of their optically configurable potential traps permits emulation of excited atomic orbitals. A classical mean field model describing the dissipative coupling mechanism between p-orbital condensates is derived, identifying lowest threshold condensation solutions as a function of trap parameters corresponding to bound and antibound $\pi$ and $\sigma$ bonding configurations, similar to those in quantum chemistry.
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光控极化子凝聚分子
提出了一种基于光捕获激子-极化子凝聚体的二维复杂分子键构型模拟凝聚态平台。极化子凝聚体在其光学可配置势阱激发态的稳定占据使得可以模拟激发态原子轨道。推导了描述p轨道凝聚体之间耗散耦合机制的经典平均场模型,确定了最低阈值凝聚解作为对应于束缚和反束缚$\pi$和$\sigma$键构型的陷阱参数的函数,类似于量子化学中的那些。
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