Synthesis, Characterization and Application of a Diatomite-Based Composite for the Adsorption of Anionic Dyes in Aqueous Solutions

IF 1 Q4 CHEMISTRY, MULTIDISCIPLINARY Chemistry & Chemical Technology Pub Date : 2021-08-15 DOI:10.23939/chcht15.03.377
Sadek Chentouf, S. Kacha, R. Marouf, Fouad Mekhalef Benhafsa, A. Leboukh, A. Yahiaoui, Scientific, Industrial Zone Bou-Ismail Tipaza Algeria Chemical Analyses
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Abstract

Synthesis, characterization and application of the polyaniline-diatomite (PAD) composite in the adsorption of Reactive Red 120 (RR 120) and Acid Blue (AB) dyes were carried out. The composite was prepared by the in situ polymerization of aniline. Mass of purified diatomite was mixed with a solution containing aniline dissolved in 2M hydrochloric acid at room temperature. The solid obtained was characterized using the SEM, XRD and FTIR analyses. The kinetic adsorption of dyes was described using the pseudo-second order kinetic model. The adsorption isotherm of the RR 120 dye can be fitted by the Freundlich adsorption isotherm model. However, the adsorption isotherm of the AB dye can be better fitted by the BET model.
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硅藻土基吸附阴离子染料复合材料的合成、表征及应用
研究了聚苯胺-硅藻土(PAD)复合材料的合成、表征及其在吸附活性红120 (RR 120)和酸性蓝(AB)染料中的应用。采用苯胺原位聚合法制备了该复合材料。在室温下,将大量纯化硅藻土与含有苯胺的盐酸溶液混合。采用扫描电镜(SEM)、x射线衍射(XRD)和红外光谱(FTIR)对所得固体进行了表征。用拟二级动力学模型描述了染料的吸附动力学。rr120染料的吸附等温线可以用Freundlich吸附等温线模型拟合。而BET模型能较好地拟合AB染料的吸附等温线。
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来源期刊
Chemistry & Chemical Technology
Chemistry & Chemical Technology CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.70
自引率
44.40%
发文量
60
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