Giant Grain Growth in (K,Na)NbO3 Ceramics

S. Park, J. W. Lee, K. Cho, Y. Min, C. Ahn
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Abstract

In this manuscript, an interesting phenomenon is reported. It has been reported that the growth of single crystals is observed in donor-doped (K,Na)NbO3 (KNN)-based ceramics. It is very interesting that the growth happens without the addition of a seed. The growth of huge grains (single crystal, approximately 30 mm,) occurs due to the abnormal grain growth (AGG) in KNN-based ceramics. In the AGG compositions, moreover, the seed plates can be synthesized by not topochemical reaction but simple molten salt synthesis (SMSS) which is a simple-and-cheap process. They can be a good candidate for the seeds at reactive templated grain growth (RTGG) or templated grain growth (TGG) process.
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(K,Na)NbO3陶瓷的巨型晶粒生长
在这份手稿中,报告了一个有趣的现象。有报道称,在给体掺杂(K,Na)NbO3 (KNN)基陶瓷中观察到单晶的生长。非常有趣的是,这种生长不需要添加种子。在knn基陶瓷中,由于晶粒生长异常(AGG),产生了巨大的晶粒(单晶,约30 mm)。此外,在AGG组合物中,种子板可以通过简单熔盐合成(SMSS)而不是拓扑化学反应来合成,这是一种简单而廉价的方法。它们可以作为活性模板粒生长(RTGG)或模板粒生长(TGG)过程中的种子候选材料。
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