Extraction of Yttrium from Ferruginous Sandstone, Southwestern Sinai, Egypt

H. M. Salman, O. Hussaini, N. Fattah, M. Mahmoud
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引用次数: 3

Abstract

The Ferruginous sandstone ore was obtained from Ramlet Hemeyir area, Southwestern Sinai, Egypt,which contains 10%(REE) rare earth elements. A representative sample has been subjected to acid agitation leaching usingH 2SO4where 93%of the REE contentwas released bymixing the ground sample to (-100mesh) with concentrated H2SO4 at solid/liquid (S/L) ratio of 1/2 for 5h at a temperature ranged from(250 - 300oC). The REEwas precipitated in the oxalate formfromthe prepared sulfate leach liquor.Next selective extraction of 98%Ywas achieved by contactingYwas extracted by di-(2-ethylhexyl)phosphoric acid (D2EHPA) with the aqueous solution of nitric acid leaching of the REE cake. Stripping was done by hot H2O (80 oC). Finally, a precipitation with oxalic acid was done followed by ignition at 950oC.Ayield of 95%Yoxide was produced.
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埃及西奈西南部含铁砂岩中钇的提取
该含铁砂岩矿石产于埃及西奈西南部Ramlet Hemeyir地区,稀土元素含量为10%(REE)。一个有代表性的样品使用H2SO4进行酸搅拌浸出,其中93%的REE含量通过将地面样品与浓H2SO4混合到(-100目),固液比(S/L)为1/2,在温度范围为(250 - 300℃)的5h中释放出来。从制备的硫酸盐浸出液中以草酸盐形式析出稀土。用二-(2-乙基己基)磷酸(D2EHPA)与硝酸浸出稀土矿饼的水溶液接触,可选择性提取98%的稀土。溶出用热水(80℃)进行。最后,草酸沉淀,950℃点火。产率达95%。
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Extraction of Yttrium from Ferruginous Sandstone, Southwestern Sinai, Egypt
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