Crush and Acid Resistance of Microsphere Narrow Fractions from Fly Ash as the Basis of Composite Materials

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY Journal of Siberian Federal University. Chemistry Pub Date : 2020-06-01 DOI:10.17516/1998-2836-0174
G. Akimochkina, E. S. Rogovenko, E. Fomenko
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Abstract

The crush test and acid resistance of microsphere narrow fractions with average diameter dav of 5, 8 and 25 μm of the SiO2–Al2O3–FeO system and with dav of 4 and 10 μm the CaO–SiO2–Al2O3– FeO system separated from fly ash from pulverized combustion of Ekibastuz and Irsha-Borodinsky coals were studied. It has been established that all investigated ash fractions of both raw materials are characterized by high strength: microspheres of a larger narrow fraction with dav = 25 μ m a re not destroyed by compressive loading at pressures up to 51.7 MPa, dispersed narrow fractions of microspheres with dav ≤ 10 μm – up to 68.9 MPa. Microsphere narrow fractions with aluminosilicate composition have satisfactory acid resistance; the weight loss after treatment with 15 % hydrochloric acid at 65 °C for 30 minutes was 10–15 wt. %
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粉煤灰微球窄组分作为复合材料基础的抗压耐酸性能
研究了Ekibastuz和irshaborodinsky煤燃烧后粉煤灰中SiO2-Al2O3-FeO体系平均粒径为5、8和25 μm的微球窄馏分,以及粒径为4和10 μm的CaO-SiO2-Al2O3 - FeO体系的破碎试验和耐酸性能。结果表明,两种原料的灰分均具有较高的强度特征:在51.7 MPa压力下,dav = 25 μm的较大窄段微球不会被压缩载荷破坏,dav≤10 μm的分散窄段微球在68.9 MPa压力下不会被破坏。铝硅酸盐组成的微球窄馏分具有良好的耐酸性能;用15%盐酸在65°C下处理30分钟后,体重减轻10-15 wt. %
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13
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